Ferrocene-based phosphonite-phosphine ligands, Pd and Rh complexes

被引:31
作者
Laly, M [1 ]
Broussier, R [1 ]
Gautheron, B [1 ]
机构
[1] CNRS, Lab Synth & Electrosynth Organomet, F-21000 Dijon, France
关键词
ferrocenes; phosphine; phosphonite; palladium catalysts; rhodium catalysts;
D O I
10.1016/S0040-4039(99)02276-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A variety of ferrocene-based 1-phosphonite- 1'-phosphine ligands were prepared via 1-dichlorophosphino-1'-diphenylphosphinoferrocene from anionic ring opening of 1-phenyl-1-phospha-[1]ferrocenophane. The corresponding palladium and rhodium complexes have also been prepared and tested, respectively, in Heck and hydroformylation reactions. (C) 2000 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1183 / 1185
页数:3
相关论文
共 20 条
[1]   NEUTRAL RHODIUM(I) AMINOPHOSPHINE-PHOSPHINITE COMPLEXES - SYNTHESIS, STRUCTURE, AND USE IN CATALYTIC ASYMMETRIC HYDROGENATION OF ACTIVATED KETO COMPOUNDS - CRYSTAL-STRUCTURE OF [(S)-1-(DICYCLOHEXYLPHOSPHINO)-2-(((DICYCLOHEXYLPHOSPHINO)OXY)METHYL)-PYRROLIDINE](2,4-PENTANEDIOMATO-O,O')RHODIUM(I) [J].
AGBOSSOU, F ;
CARPENTIER, JF ;
HATAT, C ;
KOKEL, N ;
MORTREUX, A ;
BETZ, P ;
GODDARD, R ;
KRUGER, C .
ORGANOMETALLICS, 1995, 14 (05) :2480-2489
[2]   Palladium (II) complexes of (diisopropylphosphino)-ferrocenes: improved catalysts for the Heck reaction [J].
Boyes, AL ;
Butler, IR ;
Quayle, SC .
TETRAHEDRON LETTERS, 1998, 39 (42) :7763-7766
[3]  
Butler IR, 1996, SYNTHESIS-STUTTGART, P1350
[4]   A molecular model to explain and predict the stereoselectivity in rhodium-catalyzed hydroformylation [J].
Gleich, D ;
Schmid, R ;
Herrmann, WA .
ORGANOMETALLICS, 1998, 17 (11) :2141-2143
[5]   THERMAL RING-OPENING POLYMERIZATION (ROP) OF STRAINED, RING-TILTED, PHOSPHORUS-BRIDGED [1]FERROCENOPHANES - SYNTHESIS OF POLY(FERROCENYLPHOSPHINES) AND POLY(FERROCENYLPHOSPHINE SULFIDES) [J].
HONEYMAN, CH ;
FOUCHER, DA ;
DAHMEN, FY ;
RULKENS, R ;
LOUGH, AJ ;
MANNERS, I .
ORGANOMETALLICS, 1995, 14 (12) :5503-5512
[6]   Asymmetric hydroformylation of heterocyclic olefins catalyzed by chiral phosphine-phosphite-Rh(I) complexes [J].
Horiuchi, T ;
Ohta, T ;
Shirakawa, E ;
Nozaki, K ;
Takaya, H .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (13) :4285-4292
[7]   Chiral phosphinephosphites having axial and central chirality in asymmetric hydroformylations [J].
Kless, A ;
Holz, J ;
Heller, D ;
Kadyrov, R ;
Selke, R ;
Fischer, C ;
Borner, A .
TETRAHEDRON-ASYMMETRY, 1996, 7 (01) :33-36
[8]   A NOVEL METHOD TO SYNTHESIZE UNSYMMETRICAL DISUBSTITUTED FERROCENES [J].
LAI, LL ;
DONG, TY .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (20) :2347-2348
[9]   Complexation on rhodium of bidentate and potentially hemilabile phosphorous ligands [J].
Le Gall, I ;
Laurent, P ;
Soulier, E ;
Salaun, JY ;
des Abbayes, H .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 567 (1-2) :13-20
[10]   Ferrocenyl diphosphines containing stereogenic phosphorus atoms.: Synthesis and application in the rhodium-catalyzed asymmetric hydrogenation [J].
Maienza, F ;
Wörle, M ;
Steffanut, P ;
Mezzetti, A ;
Spindler, F .
ORGANOMETALLICS, 1999, 18 (06) :1041-1049