A Ring-Opening Metathesis Polymerization Route to Alkaline Anion Exchange Membranes: Development of Hydroxide-Conducting Thin Films from an Ammonium-Functionalized Monomer

被引：220

作者：

Clark, Timothy J. ^{[1
]}

Robertson, Nicholas J. ^{[1
]}

Kostalik, Henry A. ^{[1
]}

Lobkovsky, Emil B. ^{[1
]}

Mutolo, Paul F. ^{[1
]}

Abruna, Hector D. ^{[1
]}

Coates, Geoffrey W. ^{[1
]}

机构：

[1] Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 36期

基金：

加拿大自然科学与工程研究理事会;

关键词：

FUEL-CELLS; TEMPERATURE; POLYMERS;

D O I：

10.1021/ja905242r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the development of a facile ring-opening olefin metathesis route to alkaline anion exchange membranes via the copolymerization of a tetraalkylammonium-functionalized norbornene with dicyclopentadiene. The thin films generated are mechanically strong and exhibit high hydroxide conductivities and exceptional methanol tolerance.

引用

页码：12888 / +

页数：3

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