A practical synthetic method for α- and β-glycosyloxyacetic acids

被引：7

作者：

Mandai, T

Okumoto, H

Oshitari, T

Nakanishi, K

Mikuni, K

Hara, KJ

Hara, KZ

机构：

[1] Kurashiki Univ Sci & Arts, Dept Chem Technol, Kurashiki, Okayama 7128505, Japan

[2] Biores Corp Yokohama, Tsurumi Ku, Yokohama, Kanagawa 2300053, Japan

来源：

HETEROCYCLES | 2000年 / 52卷 / 01期

关键词：

D O I：

10.3987/COM-99-S43

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dihydroxylation of allyl 2,3,4-tri-O-benzyl-6-O-tritylglycosides provides diols, the anomers of which can easily be separated by column chromatography in a practical scale. These anomers can be cleanly transformed into alpha- and beta-glycosyloxyacetic acids, respectively, via oxidative cleavage of the diol followed by oxidation.

引用

页码：129 / 132

页数：4