The infinite one-dimensional chain polymer catena-poly[[bis[μ-1,1′-ethane-1,2-diylbis(1,2,4-triazole)-κ2N4:N4′]bis[azidozinc(II)]]-di-μ-azido-κ4N1:N1]

被引：24

作者：

Zhu, X ^{[1
]}

Li, BZ ^{[1
]}

Zhou, JH ^{[1
]}

Li, BL ^{[1
]}

Zhang, Y ^{[1
]}

机构：

[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/s0108270104005542

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the crystal structure of the title complex, [Zn(N-3)(2)( C6H8N6)](n) or [Zn(N-3)(2)(bte)](n), where bte is mu-1,2-bis(1,2,4-triazol- 1-yl) ethane, each Zn atom is pentacoordinated in a distorted trigonal-bipyramidal coordination environment involving two N atoms from two bte ligands and three N atoms from three azide ligands. The Zn atoms are bridged by mu-1,1-azide groups and bte ligands around a centre of inversion, forming an infinite one-dimensional chain containing both four-membered Zn(mu-1,1-N-3)(2)Zn and 18-membered Zn(gauche-bte)(2)Zn rings.

引用

页码：M191 / M193

页数：3

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