t-BuOK-catalyzed addition phosphines to functionalized alkenes:: a convenient synthesis of polyfunctional phosphine derivatives

被引：105

作者：

Bunlaksananusorn, T ^{[1
]}

Knochel, P ^{[1
]}

机构：

[1] Univ Munich, Inst Organ Chem, D-81377 Munich, Germany

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 33期

关键词：

addition reaction; phosphine ligands; diphosphines; functionalized phosphines;

D O I：

10.1016/S0040-4039(02)01177-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of t-BuOK in DMSO allows a smooth addition of Ph2PH, Cy2PH and Ph2P(O)H to various functionalized alkenes leading to poly functional phosphines in good yields. This method has been used to prepare precursors for P,P- and P,N-ligands. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：5817 / 5819

页数：3

共 24 条

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