Unique asymmetric catalysis of cis-β metal complexes of salen and its related Schiff-base ligands

被引：320

作者：

Katsuki, T ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch, Fac Sci, Dept Chem,Higashi Ku, Fukuoka 8128581, Japan

来源：

CHEMICAL SOCIETY REVIEWS | 2004年 / 33卷 / 07期

关键词：

D O I：

10.1039/b304133f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexes of chiral salen and its related tetradentate Schiff-base ligands adopt three different configurations, trans, cis-alpha and cis-beta. Of these complexes, trans-complexes have been widely used as catalysts for various asymmetric reactions. However, recent studies have disclosed that cis-beta metallosalen and its related complexes show unique asymmetric catalyses that cannot be achieved by trans-metallosalen complexes. The present article summarizes generation of cis-beta metallosalen and its related complexes, their structural features, and their application to asymmetric syntheses.

引用

页码：437 / 444

页数：8

共 38 条

[1]

Aly MM, 1996, REV INORG CHEM, V16, P315

[2]

Beller M., 1998, TRANSITION METALS OR, V2

[3]

Belokon' YN, 2000, EUR J ORG CHEM, V2000, P2655

[4] LIGAND PROPERTIES OF QUADRIDENTATE SCHIFFS BASES - CRYSTAL AND MOLECULAR STRUCTURE OF MIXED-LIGAND COMPLEX [NN'-ETHYLENEBIS-(SALICYLIDENEIMINATO)](ACETYLACETONATO)COBALT(III)-0.7 WATER [J].

CALLIGARIS, M ;

MANZINI, G ;

RANDACCIO, L ;

NARDIN, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (04) :543-+

[5] STRUCTURAL ASPECTS OF METAL-COMPLEXES WITH SOME TETRADENTATE SCHIFF-BASES [J].

CALLIGARIS, M ;

RANDACCIO, L ;

NARDIN, G .

COORDINATION CHEMISTRY REVIEWS, 1972, 7 (04) :385-+

[6] Metal complexes of chiral binaphthyl Schiff-base ligands and their application in stereoselective organic transformations [J].

Che, CM ;

Huang, JS .

COORDINATION CHEMISTRY REVIEWS, 2003, 242 (1-2) :97-113

[7] CIS-DICHLORO-DERIVATIVES AND TRANS-DICHLORO-DERIVATIVES OF 6-CO-ORDINATED AND 7-CO-ORDINATE ZIRCONIUM AND HAFNIUM BONDED TO QUADRIDENTATE SCHIFF-BASE LIGANDS - CRYSTAL-STRUCTURES OF [ZR(ACEN)CL2(THF)], [M(SALPHEN)CL2(THF)].0.5THF, [M(ACEN)CL2], (M = ZR OR HF), AND [ZR(MSAL)CL2] [ACEN = N,N'-ETHYLENEBIS(ACETYLACETONEIMINATE), SALPHEN = N,N'-ORTHO-PHENYLENEBIS(SALICYLIDENEIMINATE), MSAL = N-METHYLSALICYLIDENEIMINATE, AND THF = TETRAHYDROFURAN] [J].

CORAZZA, F ;

SOLARI, E ;

FLORIANI, C ;

CHIESIVILLA, A ;

GUASTINI, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (04) :1335-1344

[8] Stereochemical control of cis- and trans-TiCl2 groups in six-coordinate complexes [(L)TiCl2] (L2- = N2O2-donor Schiff base) and reactions with trimethylaluminium to form cationic aluminium species [J].

Corden, JP ;

Errington, W ;

Moore, P ;

Wallbridge, MGH .

CHEMICAL COMMUNICATIONS, 1999, (04) :323-324

[9] Asymmetric catalysis of epoxide ring opening reactions [J].

Jacobsen, EN .

ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (06) :421-431

[10]

JACOBSEN EN, 1993, CATALYTIC ASYMMETRIC, P159

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