Palladium and rhodium complexes of a chiral pincer ligand derived from 1,3-trans disubstituted cyclohexane

被引：36

作者：

Kuznetsov, Vladimir F.

Lough, Alan J.

Gusev, Dmitry G.

机构：

[1] Wilfrid Laurier Univ, Dept Chem, Waterloo, ON N2L 3C5, Canada

[2] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 09期

基金：

加拿大自然科学与工程研究理事会;

关键词：

chiral phosphine; pincer ligand; DFT calculation; rhodium and palladium complexes; C-H activation;

D O I：

10.1016/j.ica.2005.11.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of cis- and trans-1, 3-bis(di-t-butylphosphinomethyl)cyclohexane (cis- and trans-PCyP), with rhodium and palladium chlorides afforded C-s and C-1 symmetrical pincer complexes, RhHCl(cis-PCyP), RhHCl(trans-PCyP), [(COD)Rh( mu-Cl)(2)RhH(trans-PCyP)], PdCl(cis-PCyP), and PdCl(trans-PCyP), where the PCyP ligands are coordinated in a meridianal fashion through the two phosphorus atoms and the cyclometalated C-1 carbon of the cyclohexane ring. The rhodium complexes were structurally characterized by X-ray diffraction. Isomers of the RhHCl(PCyP) and PdCl(PCyP) complexes were studied by DFT calculations. (c) 2005 Elsevier B.V. All rights reserved.

引用

收藏

页码：2806 / 2811

页数：6

相关论文

共 20 条

[1] Exchange functionals with improved long-range behavior and adiabatic connection methods without adjustable parameters:: The mPW and mPW1PW models [J].

Adamo, C ;

Barone, V .

JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (02) :664-675

[2] REACTION OF H-2 WITH IRHCL2P2 (P = P(I)PR(3) OR P(T)BU2PH) - STEREOELECTRONIC CONTROL OF THE STABILITY OF MOLECULAR H-2 TRANSITION-METAL COMPLEXES [J].

ALBINATI, A ;

BAKHMUTOV, VI ;

CAULTON, KG ;

CLOT, E ;

ECKERT, J ;

EISENSTEIN, O ;

GUSEV, DG ;

GRUSHIN, VV ;

HAUGER, BE ;

KLOOSTER, WT ;

KOETZLE, TF ;

MCMULLAN, RK ;

OLOUGHLIN, TJ ;

PELISSIER, M ;

RICCI, JS ;

SIGALAS, MP ;

VYMENITS, AB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (16) :7300-7312

[3]

Boeseken J, 1925, RECL TRAV CHIM PAY-B, V44, P841

[4]

Burke K., 1998, ELECT DENSITY FUNCTI

[5] RAPID REVERSIBLE FISSION OF A C-H BOND IN A METAL-COMPLEX - X-RAY CRYSTAL-STRUCTURE OF [RHHCL(BUT2PCH2CH2CHCH2CH2PBUT2)] [J].

CROCKER, C ;

ERRINGTON, RJ ;

MCDONALD, WS ;

ODELL, KJ ;

SHAW, BL ;

GOODFELLOW, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (11) :498-499

[6] Transcyclometalation:: A novel route to (Chiral) bis-ortho-chelated bisphosphinoaryl ruthenium(II) complexes [J].

Dani, P ;

Albrecht, M ;

van Klink, GPM ;

van Koten, G .

ORGANOMETALLICS, 2000, 19 (22) :4468-4476

[7]

FRISH A, 2003, GAUSSIAN 03 USERS RE

[8] SYNTHESIS OF AN OPTICALLY-ACTIVE PLATINUM(II) COMPLEX CONTAINING A NEW TERDENTATE P-C-P LIGAND AND ITS CATALYTIC ACTIVITY IN THE ASYMMETRIC ALDOL REACTION OF METHYL ISOCYANOACETATE - X-RAY CRYSTAL-STRUCTURE OF [2,6-BIS[1'S,2'S)-1'-(DIPHENYLPHOSPHINO)-2',3'-O-ISOPROPYLIDENE-2',3'-DIHYDROXYPROPYL[PHENYL](ETA'-NITRATO)PLATINUM(II) [J].

GORLA, F ;

TOGNI, A ;

VENANZI, LM ;

ALBINATI, A ;

LIANZA, F .

ORGANOMETALLICS, 1994, 13 (05) :1607-1616

[9] ALICYCLIC GLYCOLS .9. 1-3-BISHYDROXYMETHYLCYCLOHEXANE [J].

HAGGIS, GA ;

OWEN, LN .

JOURNAL OF THE CHEMICAL SOCIETY, 1953, (FEB) :399-403

[10] H-2 BINDING TO AND FLUXIONAL BEHAVIOR OF IR(H)2X(PTBU2R)2 (X=CL, BR, I R=ME, PH) [J].

HAUGER, BE ;

GUSEV, D ;

CAULTON, KG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (01) :208-214