Reactions of copper(I) halides with tertiary phosphines. The unique structure of [Cu(tribenzylphosphine)(2)][CuBr2]

被引：19

作者：

Akrivos, PD

Karagiannidis, PP

Raptopoulou, CP

Terzis, A

Stoyanov, S

机构：

[1] ARISTOTELIAN UNIV THESSALONIKI,DEPT CHEM,INORGAN CHEM LAB,GR-54006 THESSALONIKI,GREECE

[2] NCSR DEMOKRITOS,INST SCI MAT,GR-15310 ATHENS,GREECE

[3] UNIV SOFIA,ST KLIMENT OKHRIDSKII,DEPT CHEM,BU-1126 SOFIA,BULGARIA

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 13期

关键词：

D O I：

10.1021/ic951387n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper(I) bromide reacts under atmospheric conditions with tribenzylphdsphine; PBz3, in acetonitrile according to the following reaction scheme: 2CuBr + 2PB(z3) --> [CU(PBZ3)(2)][CUBr2]. The product, identified by spectroscopic techniques and X-ray diffraction, is the first known example of an ionic copper(I) compound with a tertiary phosphine which possesses a linear CuP2 coordination environment.

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页码：4082 / &

页数：3

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