Reactions of copper(I) halides with tertiary phosphines. The unique structure of [Cu(tribenzylphosphine)(2)][CuBr2]

被引:19
作者
Akrivos, PD
Karagiannidis, PP
Raptopoulou, CP
Terzis, A
Stoyanov, S
机构
[1] ARISTOTELIAN UNIV THESSALONIKI,DEPT CHEM,INORGAN CHEM LAB,GR-54006 THESSALONIKI,GREECE
[2] NCSR DEMOKRITOS,INST SCI MAT,GR-15310 ATHENS,GREECE
[3] UNIV SOFIA,ST KLIMENT OKHRIDSKII,DEPT CHEM,BU-1126 SOFIA,BULGARIA
关键词
D O I
10.1021/ic951387n
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Copper(I) bromide reacts under atmospheric conditions with tribenzylphdsphine; PBz3, in acetonitrile according to the following reaction scheme: 2CuBr + 2PB(z3) --> [CU(PBZ3)(2)][CUBr2]. The product, identified by spectroscopic techniques and X-ray diffraction, is the first known example of an ionic copper(I) compound with a tertiary phosphine which possesses a linear CuP2 coordination environment.
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页码:4082 / &
页数:3
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