Preparation of poly(beta-malic acid) by enzymatic ring-opening polymerization of benzyl beta-malolactonate

被引:47
作者
Matsumura, S
Beppu, H
Nakamura, K
Osanai, S
Toshima, K
机构
[1] Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Yokohama 223, 3-14-1, Hiyoshi, Kohoku-ku
关键词
D O I
10.1246/cl.1996.795
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Poly(beta-malic acid) was prepared by lipase-catalyzed ring-opening polymerization of benzyl beta-malolactonate with subsequent debenzylation. Benzyl beta-malolactonate was readily polymerized by porcine pancreatic lipase or Novozyme 435 lipase at 60 degrees C to yield poly(benzyl beta-malate) having a molecular weight of greater than 7000.
引用
收藏
页码:795 / 796
页数:2
相关论文
共 9 条
[1]  
ABE Y, 1986, YUKAGAKU, V35, P937
[2]   SYNTHESIS OF STEREOREGULAR POLY(ALKYL MALOLACTONATES) [J].
ARNOLD, SC ;
LENZ, RW .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1986, 6 :285-303
[3]   OPTICALLY-ACTIVE POLY (BETA-MALIC-ACID) [J].
GUERIN, P ;
VERT, M ;
BRAUD, C ;
LENZ, RW .
POLYMER BULLETIN, 1985, 14 (02) :187-192
[4]  
Kawai F, 1995, Adv Biochem Eng Biotechnol, V52, P151
[5]   ENZYME-CATALYZED EPSILON-CAPROLACTONE RING-OPENING POLYMERIZATION [J].
MACDONALD, RT ;
PULAPURA, SK ;
SVIRKIN, YY ;
GROSS, RA ;
KAPLAN, DL ;
AKKARA, J ;
SWIFT, G ;
WOLK, S .
MACROMOLECULES, 1995, 28 (01) :73-78
[6]  
OUCHI T, 1989, MAKROMOL CHEM, V190, P1523
[7]   WATER-SOLUBLE POLYMERS [J].
SWIFT, G .
POLYMER DEGRADATION AND STABILITY, 1994, 45 (02) :215-231
[8]   ENZYMATIC RING-OPENING POLYMERIZATION OF LACTONES CATALYZED BY LIPASE [J].
UYAMA, H ;
KOBAYASHI, S .
CHEMISTRY LETTERS, 1993, (07) :1149-1150
[9]  
Vert M., 1979, Am Chem Soc Div Polym Chem Prepr, V20, P608