Raman spectra of light and heavy water in the O-H and O-D stretching vibrations region

被引:31
作者
Chumaevskii, NA [1 ]
Rodnikova, MN [1 ]
Sirotkin, DA [1 ]
机构
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia
关键词
D O I
10.1016/S0167-7322(99)00040-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
New experimental data on O-H and O-D stretching vibrations were received from Raman spectra of light and heavy water and aqueous solutions of some electrolytes. These data permit to estimate previous results in this field from a new position. Our results were explained from the point of view of rotational reorientation of the central water molecules in the five-molecule structural units. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:39 / 46
页数:8
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