Luminescent properties of Eu3+ activated MLa2(MoO4)4 based (M = Ba, Sr and Ca) novel red-emitting phosphors

被引:81
作者
Haque, Md. Masuqul [1 ]
Kim, Dong-Kuk [1 ]
机构
[1] Kyungpook Natl Univ, Dept Chem, Taegu 702701, South Korea
关键词
Rare earth compounds; Phosphors; Luminescence; Light emitting diodes;
D O I
10.1016/j.matlet.2009.01.018
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Eu3+-activated novel red phosphors, MLa2(MoO4)(4) (M = Ba, Sr and Ca) were synthesized by the conventional solid state method. The excitation and emission spectra indicate that these phosphors can be effectively excited by UV (395 nm) and blue (466 nm) light, and exhibit a satisfactory red performance at 614 nm. Upon excitation with a 466 nm light, Our synthesized phosphors have stronger emission intensity than the sulfide red phosphors used in white LEDs. Due to high emission intensity and a good excitation profile, the Eu3+-doped CaLa2(MoO4)(4) phosphor may be a promising candidate in solid-state lighting applications. (c) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:793 / 796
页数:4
相关论文
共 18 条
[1]   THE CRITICAL CONCENTRATION FOR QUENCHING OF THE EU3+ LUMINESCENCE IN SOME GD3+ EU3+ SYSTEMS [J].
BERDOWSKI, PAM ;
BLASSE, G .
JOURNAL OF SOLID STATE CHEMISTRY, 1986, 63 (01) :86-88
[2]  
Blasse G., 1994, LUMINESCENT MAT, P27
[3]   The optical spectroscopy of lanthanides R3+ in ABi(XO4)2 (A = Li, Na; X = Mo, W) and LiYb(MoO4)2 multifunctional single crystals:: Relationship with the structural local disorder [J].
Cascales, C ;
Blas, AM ;
Rico, M ;
Volkov, V ;
Zaldo, C .
OPTICAL MATERIALS, 2005, 27 (11) :1672-1680
[4]   Structural, spectroscopic and photolurninescence studies of LiEu(WO4)2-x(MoO4), as a near-UV convertible phosphor [J].
Chiu, Chuang-Hung ;
Wang, Ming-Fang ;
Lee, Chi-Shen ;
Chen, Teng-Ming .
JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (02) :619-627
[5]  
Dalmasso S, 2002, PHYS STATUS SOLIDI A, V192, P139, DOI 10.1002/1521-396X(200207)192:1<139::AID-PSSA139>3.0.CO
[6]  
2-G
[7]   Methods to improve the fluorescence intensity of CaS:Eu2+ red-emitting phosphor for white LED [J].
Guo, Chongfeng ;
Huang, Dexiu ;
Su, Qiang .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2006, 130 (1-3) :189-193
[8]   Characterization and properties of green-emitting β-SiAlON:Eu2+ powder phosphors for white light-emitting diodes -: art. no. 211905 [J].
Hirosaki, N ;
Xie, RJ ;
Kimoto, K ;
Sekiguchi, T ;
Yamamoto, Y ;
Suehiro, T ;
Mitomo, M .
APPLIED PHYSICS LETTERS, 2005, 86 (21) :1-3
[9]   Fabrication of Eu3+ and SM3+ codoped micro/nanosized MMoO4 (M = Ca, Ba, and Sr) via facile hydrothermal method and their photoluminescence properties through energy transfer [J].
Jin, Ye ;
Zhang, Jiahua ;
Lu, Shaozhe ;
Zhao, Haifeng ;
Zhang, Xia ;
Wang, Xiao-Jun .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (15) :5860-5864
[10]   THE LUMINESCENCE OF DOPED AND UNDOPED BALN2(MOO4)4 (LN = LA,GD) [J].
KELLER, RCA ;
BLASSE, G ;
LINDHOLM, T ;
LESKELA, M .
MATERIALS CHEMISTRY AND PHYSICS, 1988, 20 (06) :589-598