Ionic Liquid (1-Methyl 3-propyl imidazolium iodide) With Polymer Electrolyte for DSSC Application

被引:30
作者
Singh, Pramod K. [1 ]
Kim, Kang-Wook [1 ]
Rhee, Hee-Woo [1 ]
机构
[1] Sogang Univ, Dept Chem & Biomol Engn, Seoul, South Korea
关键词
SOLAR-CELLS; SOLVENT-FREE; COMPOSITE;
D O I
10.1002/pen.21212
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Polymer electrolytes based on poly(ethylene oxide) and ionic liquid (IL), 1-methyl 3-propyl imidazolium iodide (PMII) were prepared in film form by solution casting technique. Atomic force microscope (AFM) picture confirms the high surface roughness of films. The maximum ionic conductivity of the polymer/IL/I-2 electrolyte was 3.56 x 10(-4) S cm(-1) it room temperature. Doping of iodine in humid atmosphere formed 'fractal like structure' which affected ionic conductivity. The dye-sensitized solar cell (DSSC) using maximum ionic conductivity solid film at different humidity shows promising results. POLYM. ENG. SCI, 49:862-865, 2009. (C) 2009 Society of Plastics Engineers
引用
收藏
页码:862 / 865
页数:4
相关论文
共 19 条
[1]   EXPERIMENTAL-OBSERVATION OF LARGE-SIZE FRACTALS IN ION-CONDUCTING POLYMER ELECTROLYTE FILMS [J].
CHANDRA, A ;
CHANDRA, S .
PHYSICAL REVIEW B, 1994, 49 (01) :633-636
[2]   Anion clustering and fractal pattern growth in ion conducting polymeric matrix [J].
Chandra, A .
SOLID STATE IONICS, 1996, 86-8 :1437-1442
[3]   Facile synthesis of thick ordered mesoporous TiO2 film for dye-sensitized solar cell use [J].
Chen, Wei ;
Sun, Xiaodan ;
Cai, Qiang ;
Weng, Duan ;
Li, Hengde .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (03) :382-385
[4]   Dye-sensitized solar cells [J].
Grätzel, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (02) :145-153
[5]   Conductive polymer-carbon-imidazolium composite: a simple means for constructing solid-state dye-sensitized solar cells [J].
Ikeda, N ;
Teshima, K ;
Miyasaka, T .
CHEMICAL COMMUNICATIONS, 2006, (16) :1733-1735
[6]   A solvent-free composite polymer/inorganic oxide electrolyte for high efficiency solid-state dye-sensitized solar cells [J].
Katsaros, G ;
Stergiopoulos, T ;
Arabatzis, IM ;
Papadokostaki, KG ;
Falaras, P .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 149 (1-3) :191-198
[7]  
Keshari AK, 2008, J NANOSCI NANOTECHNO, V8, P301, DOI 10.1166/jnn.2008.003
[8]   Poly(butyl acrylate)/NaI/I2 electrolytes for dye-sensitized nanocrystalline TiO2 solar cells [J].
Kim, JH ;
Kang, MS ;
Kim, YJ ;
Won, J ;
Kang, YS .
SOLID STATE IONICS, 2005, 176 (5-6) :579-584
[9]   Review of recent progress in solid-state dye-sensitized solar cells [J].
Li, B ;
Wang, LD ;
Kang, BN ;
Wang, P ;
Qiu, Y .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2006, 90 (05) :549-573
[10]  
Longo C, 2003, J BRAZIL CHEM SOC, V14, P889