Trinuclear complexes containing incomplete cubane CoIII3O4 cores.: Structures of the isomers of the N-(2-pyridylmethyl)glycinato complex

被引：5

作者：

Ama, Tomoharu ^{[1
]}

Yonemura, Toshiaki ^{[1
]}

Yamaguchi, Masayoshi ^{[1
]}

机构：

[1] Kochi Univ, Fac Sci, Dept Mat Sci, Kochi 7808520, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2006年 / 79卷 / 07期

关键词：

D O I：

10.1246/bcsj.79.1063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two isomers of N-(2-pyridylmethyl)glycinatocobalt(III) complexes containing incomplete cubane Co3O4 cores, [Co-3(Pg)(3)(mu(3)-O)(mu-oH)(3)](+), were isolated and their structures were determined by the X-ray diffraction method. While the trinuclear structure of one of the two isomers was stabilized by three inter-ligand N-(HO)-O-... hydrogen bonds, that of the other was stabilized by two N-(HO)-O-... hydrogen bonds and one inter-ligand pyridyl-pyridyl stacking interaction.

引用

页码：1063 / 1065

页数：3

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