Selective catalytic dechlorination of chloro alkanes over iron-based catalysts

被引：9

作者：

Lingaiah, N

Uddin, MA

Shiraga, Y

Tanikawa, H

Muto, A

Sakata, Y

Imai, T

机构：

[1] Okayama Univ, Fac Engn, Dept Appl Chem, Okayama 7008530, Japan

[2] Todo Kogyo Corp, Hiroshima 7390652, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 12期

关键词：

D O I：

10.1246/cl.1999.1321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A selective vapour phase dehydrochlorination (DHC) of chloro alkanes was achieved over a simple iron oxide catalyst system. The chloro alkanes were selectively dehydrochlorinated to their corresponding alkenes. This catalyst was also found to be effective for the removal of chlorine from fuel oil derived from the degradation of PVC containing waste plastics.

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页码：1321 / 1322

页数：2

相关论文

共 10 条

[1] EXHAUSTIVE LIQUID-PHASE CATALYTIC HYDRODEHALOGENATION OF CHLOROBENZENES [J].

BALKO, EN ;

PRZYBYLSKI, E ;

VONTRENTINI, F .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1993, 2 (01) :1-8

[2]

BAUSER HR, 1979, CHEMOSPHERE, V7, P415

[3] CONVERSION OF CHLOROBENZENE OVER PALLADIUM AND RHODIUM CATALYSTS OF WIDELY VARYING DISPERSION [J].

COQ, B ;

FERRAT, G ;

FIGUERAS, F .

JOURNAL OF CATALYSIS, 1986, 101 (02) :434-445

[4] VAPOR-PHASE HYDRODEHALOGENATION OF CHLOROBENZENE OVER PLATINUM/H-BEA ZEOLITE [J].

CREYGHTON, EJ ;

BURGERS, MHW ;

JANSEN, JC ;

VANBEKKUM, H .

APPLIED CATALYSIS A-GENERAL, 1995, 128 (02) :275-288

[5] CATALYTIC DEHYDROCHLORINATION OF 1,1,2-TRICHLOROETHANE OVER CSCL SUPPORTED ON SILICA-GELS [J].

MOCHIDA, I ;

TAKAGI, T ;

FUJITSU, H .

APPLIED CATALYSIS, 1985, 18 (01) :105-115

[6] Partial hydrogenation of benzene to cyclohexene [J].

Nagahara, H ;

Ono, M ;

Konishi, M ;

Fukuoka, Y .

APPLIED SURFACE SCIENCE, 1997, 121 :448-451

[7]

RYLANDER PN, 1985, HYDROGENATION METHOD, P145

[8]

SAKATA Y, 1999, AS PAC CHEM ENG S AP, P473

[9] Catalytic dehydrochlorination of 1,2-dichloroethane over pyridine deposited pitch-based active carbon fiber [J].

Sotowa, C ;

Kawabuchi, Y ;

Mochida, I .

CHEMISTRY LETTERS, 1996, (11) :967-968

[10] Direct formation of cyclohexene via the gas phase catalytic dehydrohalogenation of cyclohexyl halides [J].

Tavoularis, G ;

Keane, MA .

APPLIED CATALYSIS A-GENERAL, 1999, 182 (02) :309-316