Studies of rhodium-catalyzed ring opening of vinyl epoxides

被引：28

作者：

Ha, JD ^{[1
]}

Shin, EY ^{[1
]}

Kang, SK ^{[1
]}

Ahn, JH ^{[1
]}

Choi, JK ^{[1
]}

机构：

[1] Korea Res Inst Chem Technol, Med Sci Div, Taejon 305600, South Korea

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 21期

关键词：

6-endo; vinyl epoxide; rhodium-catalyzed;

D O I：

10.1016/j.tetlet.2004.03.137

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stereoselective 6-endo mode cyclization of vinyl epoxides has been achieved by the use of a catalytic amount of [Rh(CO)(2)Cl](2) affording six-membered heterocycle systems, such as piperidines and tetrahydropyrans. The scope and limitations of the reaction are discussed. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：4193 / 4195

页数：3

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