Visualization of molecular recognition:: A novel system based on charge-transfer complexes composed of 1,1′-bi-2-naphthol derivatives and p-benzoquinone

被引:51
作者
Imai, Yoshitane
Tajima, Nobuo
Sato, Tomohiro
Kuroda, Reiko
机构
[1] SORST Kuroda Chiromorphol Team, JST ERATO, Meguro Ku, Tokyo 1530041, Japan
[2] Univ Tokyo, Grad Sch Art & Sci, Dept Life Sci, Meguro Ku, Tokyo 1538902, Japan
关键词
D O I
10.1021/ol060862q
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Charge-transfer (CT) complexes composed of 1,1-bi-2-naphthol derivatives as an electron donor and p-benzoquinone as an acceptor serve as an excellent host system for visual molecular recognition. This is because they form inclusion crystals with guest aromatic compounds which display remarkably different colors depending on the structure of the component molecules and on the method of crystallization (i.e., solution crystallization or solid cogrinding of component crystals).
引用
收藏
页码:2941 / 2944
页数:4
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