Chemistry of functionalized thiolates:: syntheses and structures of neutral, monomeric [Zn(SC6H4X-4)2(N-N)], where X = H, NH2 and OH, and (N-N) = nitrogen bases 2,2′-bpy, phen and tmen

被引:21
作者
Anjali, KS [1 ]
Sampanthar, JT [1 ]
Vital, JJ [1 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore
关键词
crystal structures; zinc complexes; thiolate complexes;
D O I
10.1016/S0020-1693(99)00267-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Six neutral monomers of the type [Zn(SC6H4X-4)(2)(N-N)] (where X = H, NH2, OH; (N-N) = tetramethylethylenediamine (tmen); 2,2'-bipyridyl (bpy) and 1,10-phenanthroline (phen)) have been synthesized in quantitative yield by reacting bis(4-substituted benzenethiolato)zinc(II) with an equimolar amount of the dinitrogen bases. The crystal and molecular structures of all the compounds were determined by X-ray crystallography. A simple neutral compound [Zn(SPh)(2)(bpy)] was also prepared for comparison. The compounds show some interesting X-H ... S (where X=O or N) hydrogen bonding pattern in the solid state. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:9 / 17
页数:9
相关论文
共 25 条
  • [1] THE DEVELOPMENT OF VERSION-3 AND VERSION-4 OF THE CAMBRIDGE STRUCTURAL DATABASE SYSTEM
    ALLEN, FH
    DAVIES, JE
    GALLOY, JJ
    JOHNSON, O
    KENNARD, O
    MACRAE, CF
    MITCHELL, EM
    MITCHELL, GF
    SMITH, JM
    WATSON, DG
    [J]. JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1991, 31 (02): : 187 - 204
  • [2] [Anonymous], 1996, SHELXTL REF MAN VERS
  • [3] SYNTHESIS OF LOW-COORDINATE CHALCOGENOLATO COMPLEXES OF ZINC WITH O, N, S, AND P DONOR LIGANDS - MOLECULAR AND CRYSTAL-STRUCTURES OF ZN(S-T-BU3C6H2-2,4,6)2(L) (L=NC5H3ME2-2,6,PMEPH2), ZN(SE-T-BU3C6H2-2,4,6)2(OSC4H8), AND ZN(S-T-BU3C6H2-2,4,6)2(N-METHYLIMIDAZOLE)2
    BOCHMANN, M
    BWEMBYA, GC
    GRINTER, R
    POWELL, AK
    WEBB, KJ
    HURSTHOUSE, MB
    MALIK, KMA
    MAZID, MA
    [J]. INORGANIC CHEMISTRY, 1994, 33 (10) : 2290 - 2296
  • [4] VAN DER WAALS VOLUMES + RADII
    BONDI, A
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) : 441 - +
  • [5] A NEW TRIDENTATE N,N,S LIGAND AND ITS ZINC-COMPLEXES
    BRAND, U
    VAHRENKAMP, H
    [J]. INORGANIC CHEMISTRY, 1995, 34 (12) : 3285 - 3293
  • [6] CHRISTIANSON DW, 1991, ADV PROTEIN CHEM, V42, P281
  • [7] EFFECT OF N-H...S HYDROGEN-BONDING IN [(C6H11)2NH2]2[ZN2(SC6H5)6] - A MODEL FOR METALLOTHIONEIN
    CHUNG, WP
    DEWAN, JC
    WALTERS, MA
    [J]. INORGANIC CHEMISTRY, 1991, 30 (22) : 4280 - 4282
  • [8] MODELS OF LYSINE CYSTEINE HYDROGEN-BONDING IN METALLOTHIONEIN - HYDROGEN-BONDING BETWEEN AMMONIUM AND BENZENETHIOLATE IN [(C6H11)2NH2]2[CO(SC6H5)4]
    CHUNG, WP
    DEWAN, JC
    WALTERS, MA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (02) : 525 - 530
  • [9] CRYSTAL-STRUCTURES OF ZN(SR)2 COMPLEXES - STRUCTURAL MODELS FOR THE PROPOSED [ZN(CYS-S)2(HIS)2] CENTER IN TRANSCRIPTION FACTOR-IIIA AND RELATED NUCLEIC-ACID BINDING-PROTEINS
    CORWIN, DT
    KOCH, SA
    [J]. INORGANIC CHEMISTRY, 1988, 27 (03) : 493 - 496
  • [10] STRUCTURE OF (1,10-PHENANTHROLINE)BIS(4-TOLUENETHIOLATO)ZINC(II)
    CREMERS, TL
    BLOOMQUIST, DR
    WILLETT, RD
    CROSBY, GA
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (DEC): : 3097 - 3099