Effect of zinc concentration on the structural, electrical and magnetic properties of mixed Mn-Zn and Ni-Zn ferrites synthesized by the citrate precursor technique

Mixed manganese-zinc and nickel-zinc ferrites of composition Mn0.2Ni0.8-xZnxFe2O4 where x = 0.4, 0.5 and 0.6 have been synthesized by the citrate precursor technique. Decomposition of the precursor at temperatures as low as 500 degrees C gives the ferrite powder. The ferrites have been investigated for their electrical and magnetic properties such as saturation magnetization, initial permeability, Curie temperature, AC-resistivity and dielectric constant as a function of sintering temperature and zinc content. Structural properties such as lattice parameter, grain size and density are also studied. The mixed compositions exhibited higher saturation magnetizations at sintering temperatures as low as 1200 degrees C. While the Curie temperature decreased with zinc content, the permeability was found to increase. The AC-resistivity ranged from 10(5)-10(7) Omega cm and decreased with zinc content and sintering temperature. The dielectric constants were lower than those normally reported for the Mn-Zn ferrites. Samples sintered at 1400 degrees C densified to about 94% of the theoretical density and the grain size was of the order of about 1.5 mu m for the samples sintered at 1200 degrees C and increased subsequently with sintering temperature. (C) 2006 Elsevier B.V. All rights reserved.