Magnetic and structural characteristics of RCo9+delta Si4 alloys (R=Pr or Gd, delta=0-4)

被引:2
作者
Huang, MQ [1 ]
Wallace, WE [1 ]
Ma, BM [1 ]
Bounds, CO [1 ]
机构
[1] RHONE POULENC,RARE EARTHS & GALLIUM,CRANBURY,NJ 08512
关键词
D O I
10.1063/1.365148
中图分类号
O59 [应用物理学];
学科分类号
摘要
Studies of the magnetic and structural characteristics of RCo9+deltaSi4 (delta=0-4), nonstoichiometric alloys, have been extended from R=La in our earlier work to R=Pr and Gd. In the present work, as the extra Co content increases, the magnetic properties M, T-c, and H-c are significantly enhanced compared to that of the stoichiometric alloys (delta=0). Using x-ray diffraction measurements, the sublattice occupancies are calculated. The extra Co atoms are found to occupy the 4a and 16L(2) sites in the Ce2Ni17Si9 unit cell. They partially replace R and Si in these sites. (C) 1997 American Institute of Physics.
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页码:5138 / 5140
页数:3
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