Investigation of self-assembled dendrimer complexes

被引：9

作者：

Bo, ZS ^{[1
]}

Zhang, L ^{[1
]}

Wang, ZQ ^{[1
]}

Zhang, X ^{[1
]}

Shen, JC ^{[1
]}

机构：

[1] Jilin Univ, Dept Chem, Key Lab Supramol Struct & Spect, Changchun 130023, Peoples R China

来源：

MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS | 1999年 / 10卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

porphyrin; dendritic quaternary bromides; complex;

D O I：

10.1016/S0928-4931(99)00117-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Dendrimer complexes[(G-2)(4)P and (G-S)(3)P] with a porphyrin core have been prepared by self-assembling of sodium tetrakis(4-sulfonatophenyl) porphyrin with dendritic quaternary bromides (G-2 and G-3), which were synthesized by reaction of Frechet type dendritic bromides (G-2 and G-3) with triethylamine. The structure of dendrimer complexes was confirmed by H-1 NMR and element analysis. The stoichiometry rate between the dendritic quaternary bromide and porphyrin core was 4:1. Solvatochromism studies of the dendritic complexes showed that the (G-3)(4)P dendritic complex is more stable than the (G-2)(4)P dendritic complex. It is inferred that hydrophobic interactions play an important role in stabilizing these dendrimer complexes in addition to coulombic interactions. (C) 1999 Published by Elsevier Science S.A. All rights reserved.

引用

页码：165 / 170

页数：6

共 43 条

[1] MECHANISMS OF IMMUNE TOLERANCE INDUCTION THROUGH THE THYMIC - EXPRESSION OF A PERIPHERAL TISSUE-SPECIFIC PROTEIN [J].

ANTONIA, SJ ;

GEIGER, T ;

MILLER, J ;

FLAVELL, RA .

INTERNATIONAL IMMUNOLOGY, 1995, 7 (05) :715-725

[2] SYNTHESIS OF VERY HIGHLY ORDERED LIQUID-CRYSTALLINE PHASES BY COMPLEX-FORMATION OF POLYACRYLIC-ACID WITH CATIONIC SURFACTANTS [J].

ANTONIETTI, M ;

CONRAD, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (18) :1869-1870

[3] POLYELECTROLYTE-SURFACTANT COMPLEXES - A NEW-TYPE OF SOLID, MESOMORPHOUS MATERIAL [J].

ANTONIETTI, M ;

CONRAD, J ;

THUNEMANN, A .

MACROMOLECULES, 1994, 27 (21) :6007-6011

[4] GLOBULAR CARBOHYDRATE MACROMOLECULE SUGAR BALLS .1. SYNTHESIS OF NOVEL SUGAR-PERSUBSTITUTED POLY(AMIDO AMINE) DENDRIMERS [J].

AOI, K ;

ITOH, K ;

OKADA, M .

MACROMOLECULES, 1995, 28 (15) :5391-5393

[5] Synthetic carbohydrate dendrimers .1. A convergent synthesis of carbohydrate-containing dendrimers [J].

Ashton, PR ;

Boyd, SE ;

Brown, CL ;

Jayaraman, N ;

Nepogodiev, SA ;

Stoddart, JF .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (09) :1115-1128

[6] Molecular trees: A new branch of chemistry [J].

Bell, TW .

SCIENCE, 1996, 271 (5252) :1077-1078

[7] Dendrimer-metalloporphyrins: Synthesis and catalysis [J].

Bhyrappa, P ;

Young, JK ;

Moore, JS ;

Suslick, KS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (24) :5708-5711

[8]

Bo ZS, 1997, CHEM J CHINESE U, V18, P326

[9]

BRYCE MR, 1994, ANGEW CHEM INT EDIT, V33, P1761, DOI 10.1002/anie.199417611

[10]

Dandliker PJ, 1995, ANGEW CHEM INT EDIT, V34, P2725

← 1 2 3 4 5 →