Synthesis and structure of the first 2H-1,3,2-diazaphosphole complex

被引：22

作者：

Wilkens, H ^{[1
]}

Jeske, J ^{[1
]}

Jones, PG ^{[1
]}

Streubel, R ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 23期

关键词：

D O I：

10.1039/a704285j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermal decomposition of the 2H-azaphosphirene tungsten complex 1 in benzonitrile and in the presence of dimethylcyanamide yields the 2H-1,3,2-diazaphosphole tungsten complex 4, containing a novel five-membered heterocyclic ligand; the overall reaction may be described as a 1,3-dipolar cycloaddition of an in situ generated nitrilium phosphane ylide complex to benzonitrile.

引用

页码：2317 / 2318

页数：2

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