Wet Chemistry Route to Hydrophobic Blue Fluorescent Nanodiamond

被引：351

作者：

Mochalin, Vadym N. ^{[1
]}

Gogotsi, Yury ^{[1
]}

机构：

[1] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 13期

关键词：

NEAR-INFRARED FLUORESCENCE; WALLED CARBON NANOTUBES; LOW CYTOTOXICITY; GENE-EXPRESSION; IN-VIVO; DOTS; DELIVERY; POWDERS; BRIGHT; CELLS;

D O I：

10.1021/ja9004514

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrophobic blue fluorescent nanodiamond was synthesized by covalent linking of octadecylamine to the surface of nanodiamond particles. The material is easily dispersible in hydrophobic solvents, forming a transparent colloidal solution, and can be used in those applications where stable dispersions of nanodiamond in fuels, polymers or oils are required. Bright blue fluorescence of the octadecylamine-modified nanodiamond opens up new avenues for its use as a non-toxic quantum dot analogue for biomedical imaging of cellular membranes and other hydrophobic components of biological systems. Similar surface modification can be used for other carbon nanoparticles.

引用

页码：4594 / +

页数：3

共 21 条

[1] Influence of diamond powder particles on human gene expression [J].

Bakowicz-Mitura, Katarzyna ;

Bartosz, Grzegorz ;

Mitura, Stanislaw .

SURFACE & COATINGS TECHNOLOGY, 2007, 201 (13) :6131-6135

[2] Photoluminescent carbogenic dots [J].

Bourlinos, Athanasios B. ;

Stassinopoulos, Andreas ;

Anglos, Demetrios ;

Zboril, Radek ;

Georgakilas, Vasilios ;

Giannelis, Emmanuel P. .

CHEMISTRY OF MATERIALS, 2008, 20 (14) :4539-4541

[3] Solution properties of single-walled carbon nanotubes [J].

Chen, J ;

Hamon, MA ;

Hu, H ;

Chen, YS ;

Rao, AM ;

Eklund, PC ;

Haddon, RC .

SCIENCE, 1998, 282 (5386) :95-98

[4] Near-infrared fluorescence microscopy of single-walled carbon nanotubes in phagocytic cells [J].

Cherukuri, P ;

Bachilo, SM ;

Litovsky, SH ;

Weisman, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (48) :15638-15639

[5] Mammalian pharmacokinetics of carbon nanotubes using intrinsic near-infrared fluorescence [J].

Cherukuri, Paul ;

Gannon, Christopher J. ;

Leeuw, Tonya K. ;

Schmidt, Howard K. ;

Smalley, Richard E. ;

Curley, Steven A. ;

Weisman, R. Bruce .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (50) :18882-18886

[6] Characterization and application of single fluorescent nanodiamonds as cellular biomarkers [J].

Fu, Chi-Cheng ;

Lee, Hsu-Yang ;

Chen, Kowa ;

Lim, Tsong-Shin ;

Wu, Hsiao-Yun ;

Lin, Po-Keng ;

Wei, Pei-Kuen ;

Tsao, Pei-Hsi ;

Chang, Huan-Cheng ;

Fann, Wunshain .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2007, 104 (03) :727-732

[7] Active nanodiamond hydrogels for chemotherapeutic delivery [J].

Huang, Houjin ;

Pierstorff, Erik ;

Osawa, Eiji ;

Ho, Dean .

NANO LETTERS, 2007, 7 (11) :3305-3314

[8] Nanodiamond-Embedded Microfilm Devices for Localized Chemotherapeutic Elution [J].

Lam, Robert ;

Chen, Mark ;

Pierstorff, Erik ;

Huang, Houjin ;

Osawa, Eiji ;

Ho, Dean .

ACS NANO, 2008, 2 (10) :2095-2102

[9] Fluorescent carbon nanoparticles derived from candle soot [J].

Liu, Haipeng ;

Ye, Tao ;

Mao, Chengde .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (34) :6473-6475

[10]

LIU KK, 2007, NANOTECHNOLOGY, V18

← 1 2 3 →