First observation of non-bridging thiolates or tetrahedral geometries within thiolate-containing Schiff-base macrocycles: [Zn2L][CF3SO3](2)

被引：20

作者：

Brooker, S

Davidson, TC

机构：

[1] Department of Chemistry, University of Otago, Dunedin

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 20期

关键词：

D O I：

10.1039/a705415g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure determination of [Zn2L][CF3SO3](2) 1 reveals the first example of non-bridging thiolates within a thiolate-containing Schiff-base macrocyclic complex: the flexibility of such macrocycles is also clearly demonstrated as this is the first example of the provision of distorted tetrahedral metal ion binding sites.

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页码：2007 / 2008

页数：2

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