First observation of non-bridging thiolates or tetrahedral geometries within thiolate-containing Schiff-base macrocycles: [Zn2L][CF3SO3](2)

被引：20

作者：

Brooker, S

Davidson, TC

机构：

[1] Department of Chemistry, University of Otago, Dunedin

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 20期

关键词：

D O I：

10.1039/a705415g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure determination of [Zn2L][CF3SO3](2) 1 reveals the first example of non-bridging thiolates within a thiolate-containing Schiff-base macrocyclic complex: the flexibility of such macrocycles is also clearly demonstrated as this is the first example of the provision of distorted tetrahedral metal ion binding sites.

引用

页码：2007 / 2008

页数：2

共 30 条

[11]

BROOKER S, UNPUB

[12]

Brooker S., 1997, J CHEM SOC CHEM COMM, P459

[13] SYNTHESIS OF NICKEL(II), COPPER(II), ZINC(II), AND CADMIUM(II) COMPLEXES OF 2-[(2-MERCAPTOPHENYL)IMINOMETHYL]PYRROLE AND 2-[(2-MERCAPTOETHYL)-IMINOMETHYL]PYRROLE BY THE ELECTROCHEMICAL CLEAVAGE OF A DISULFIDE BOND - THE CRYSTAL-STRUCTURE OF BIS(2-[(PYRROL-2-YL)METHYLENEAMINO]THIOPHENOLATO-S,N)ZINC(II) [J].