The effect of a curing agent on the thermal degradation of fire retardant brominated epoxy resins

被引：131

作者：

Balabanovich, AI

Hornung, A

Merz, D

Seffert, H

机构：

[1] Forschungszentrum Karlsruhe, ITC TAB, D-76344 Eggenstein Leopoldshafen, Germany

[2] Belarusian State Univ, Res Inst Phys Chem Problems, Minsk 220050, BELARUS

来源：

POLYMER DEGRADATION AND STABILITY | 2004年 / 85卷 / 01期

关键词：

brominated epoxy resin; pyrolysis; GC/MS; FTIR; TG/FTIR; WEEE;

D O I：

10.1016/j.polymdegradstab.2004.02.012

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The diglycidyl ether of tetrabromobisphenol A, the diglycidyl ether of bisphenol A and their mixture was cured by 4,4'-diaminodiphenyl methane. The pyrolysis of the obtained epoxy resins was studied by TG, DSC, TG/FTIR as well as FTIR characterization of pyrolysis residues. The gaseous and high boiling pyrolysis products were collected, characterized by GC/MS and their formation is discussed. The brominated epoxy resins are thermally less stable than the non-brominated ones. This effect is caused by the amine-containing hardener. The degradation initiation reaction is associated with the formation of hydrogen bromide which further destabilizes the epoxy network. The effect of the curing agent can be used in recycling of epoxy resins to separate brominated pyrolysis products from non-brominated ones. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：713 / 723

页数：11

共 19 条

[1]

AMRCH J, 1992, ADV ORGANIC CHEM REA

[2] The effect of ammonium polyphosphate on the combustion and thermal decomposition behavior of poly(butylene terephthalate) [J].