First measurement of prenucleation molecular clusters

被引：60

作者：

Eisele, FL

Hanson, DR ^{[2
]}

机构：

[1] Georgia Inst Technol, Sch Earth & Atmospher Sci, Atlanta, GA 30332 USA

[2] Natl Ctr Atmospher Res, Div Atmospher Chem, Boulder, CO 80307 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2000年 / 104卷 / 04期

关键词：

D O I：

10.1021/jp9930651

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The molecular cluster ions HSO4-(H2SO4)(n-1) corresponding to the neutral species (H2SO4)(n) for n = 3-8 have been observed using a transverse chemical ionization scheme located inside a cooled flow tube. The contribution of ion-molecule clustering reactions was ascertained and readily separated from the ionization of the neutral clusters. The presence of the clusters was strongly dependent on temperature and humidity. Ratios of successive clusters thought to be representative of steady-state are reported.

引用

收藏

页码：830 / 836

页数：7

相关论文

共 11 条

[1] Laboratory studies of particle nucleation:: Initial results for H2SO4, H2O, and NH3 vapors [J].

Ball, SM ;

Hanson, DR ;

Eisele, FL ;

McMurry, PH .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1999, 104 (D19) :23709-23718

[2] A PRELIMINARY-STUDY OF THE EFFECT OF AMMONIA ON PARTICLE NUCLEATION IN THE MARINE BOUNDARY-LAYER [J].

COFFMAN, DJ ;

HEGG, DA .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1995, 100 (D4) :7147-7160

[3] NUCLEATION RATE IN A BINARY MIXTURE OF SULFURIC-ACID AND WATER-VAPOR [J].

JAECKERVOIROL, A ;

MIRABEL, P .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (12) :3518-3521

[4]

JEFFERSON DJ, 1997, J GEOPHYS RES, V102, P6415

[5] Parameterizations for sulfuric acid/water nucleation rates [J].

Kulmala, M ;

Laaksonen, A ;

Pirjola, L .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D7) :8301-8307

[6] NUCLEATION - MEASUREMENTS, THEORY, AND ATMOSPHERIC APPLICATIONS [J].

LAAKSONEN, A ;

TALANQUER, V ;

OXTOBY, DW .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1995, 46 :489-524

[7] Rate constants for the reactions of XO3-(H2O)(n) (X = C, HC, and N) and NO3-(HNO3)(n) with H2SO4: Implications for atmospheric detection of H2SO4 [J].

Viggiano, AA ;

Seeley, JV ;

Mundis, PL ;

Williamson, JS ;

Morris, RA .

JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (44) :8275-8278

[8] Experiments on gas-liquid nucleation of sulfuric acid and wafer [J].

Viisanen, Y ;

Kulmala, M ;

Laaksonen, A .

JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (03) :920-926

[9] Measured atmospheric new particle formation rates: Implications for nucleation mechanisms [J].

Weber, RJ ;

Marti, JJ ;

McMurry, PH ;

Eisele, FL ;

Tanner, DJ ;

Jefferson, A .

CHEMICAL ENGINEERING COMMUNICATIONS, 1996, 151 :53-64

[10] New particle formation in the remote troposphere: A comparison of observations at various sites [J].

Weber, RJ ;

McMurry, PH ;

Mauldin, RL ;

Tanner, DJ ;

Eisele, FL ;

Clarke, AD ;

Kapustin, VN .

GEOPHYSICAL RESEARCH LETTERS, 1999, 26 (03) :307-310