Characterisation of the reaction of free-base porphyrin to nitrogen dioxide

被引：11

作者：

McNaughton, A. J. ^{[1
]}

Richardson, T. H.

Barford, W.

Dunbar, A.

Hutchinson, J.

Hunter, C. A.

机构：

[1] Univ Sheffield, Dept Phys & Astron, Sheffield S3 7RH, S Yorkshire, England

[2] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2006年 / 284卷

基金：

英国工程与自然科学研究理事会;

关键词：

porphyrin; gas sensing; nitrogen dioxide;

D O I：

10.1016/j.colsurfa.2006.01.050

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The response of 5,10,15,20-tetrakis(3,4-bis[ethyl hexyloxy]phenyl)-21H,23H-porphine (EHO) to NO2 has been measured, both in solution and in Langmuir-Blodgett (LB) films. A change in the absorption spectrum has been observed, characterised by the reduction of the Soret and Q bands accompanied by the rise of two new bands at 464 and 697nm in solution. The response of free-base porphin to NO2 has been modelled using the Accelrys Materials Studio software. A good qualitative agreement can be seen between the predicted change in absorption spectrum for free-base porphin and the response observed for EHO. LB films of EHO/calixarene mixes showed a response to NO2 similar in form to the response of EHO in solution. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：345 / 349

页数：5

共 7 条

[1]

DOLPHIN D, 1978, PORPHYRINS PHYS CH A, V3

[2] Fast, reversible optical sensing of NO2 using 5,10,15,20-tetrakis[3,4-bis(2-ethylhexyloxy)phenyl]-21H,23H-porphine assemblies [J].

Dooling, CM ;

Worsfold, O ;

Richardson, TH ;

Tregonning, R ;

Vysotsky, MO ;

Hunter, CA ;

Kato, K ;

Shinbo, K ;

Kaneko, F .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (02) :392-398

[3] STUDY OF THE EFFECTS OF SUBSTITUTION ON THE ABSORPTION SPECTRA OF PORPHIN [J].

GOUTERMAN, M .

JOURNAL OF CHEMICAL PHYSICS, 1959, 30 (05) :1139-1161

[4] Inclusion phenomenon in mixed floating layers containing phthalocyanines [J].

Nabok, AV ;

Ray, AK ;

Hassan, AK ;

Omar, O ;

Taylor, R ;

Richardson, T ;

Pavier, M .

THIN SOLID FILMS, 1998, 327 :104-108

[5] Gas sensing properties of porphyrin assemblies prepared using ultra-fast LB deposition [J].

Richardson, TH ;

Dooling, CM ;

Worsfold, O ;

Jones, LT ;

Kato, K ;

Shinbo, K ;

Kaneko, F ;

Tregonning, R ;

Vysotsky, MO ;

Hunter, CA .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2002, 198 :843-857

[6] Chlorine sensing properties of porphyrin thin films [J].

Smith, VC ;

Batty, SV ;

Richardson, T ;

Foster, KA ;

Johnstone, RAW ;

Sobral, AJFN ;

Gonsalves, AMDR .

THIN SOLID FILMS, 1996, 284 :911-914

[7] OPTIMIZATION OF PARAMETERS FOR SEMIEMPIRICAL METHODS .1. METHOD [J].

STEWART, JJP .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 1989, 10 (02) :209-220

← 1 →