Reactivity of alpha-unsaturated organozinc compounds with N-(phenylsulfanyl)iminoesters - Application to the synthesis of monosubstituted or disubstituted unsaturated alpha-aminoacids

被引：10

作者：

Aidene, M ^{[1
]}

Barbot, F ^{[1
]}

Miginiac, L ^{[1
]}

机构：

[1] UNIV POITIERS,ORGAN SYNTH LAB,CNRS,URA 574,F-86022 POITIERS,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 534卷 / 1-2期

关键词：

N-(phenylsulfanyl)iminoesters; regioselectivity; allylic organozincs; allenic organozincs; alpha-aminoesters; alpha-aminoacide;

D O I：

10.1016/S0022-328X(96)06854-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new general synthesis of C-subtituted alpha-aminoacids is described, using at first the regioselective reaction between alpha-unsaturated organozincs and N-(phenylsulfanyl)iminoesters.

引用

页码：117 / 127

页数：11

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