Comparative study of PEM fuel cell storage at -20°C after gas purging

被引：33

作者：

Hou, Junbo ^{[1
]}

Yu, Hongmei

Yi, Baolian

Xiao, Yu

Wang, Hongwei

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Res & Dev Ctr, Dalian 116203, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2007年 / 10卷 / 01期

关键词：

D O I：

10.1149/1.2363952

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The effect of water removal and freeze/thaw cycles on proton exchange membrane (PEM) fuel cells was investigated by comparative study of 20 on/off and freeze/thaw cycles after purging by reactant gas with relative humidity 58.0% at 25 degrees C. Within 20 cycles, the cell performance, electrochemical active surface areas, and electrochemical impedance spectra responses were analyzed by the mean squared deviation method. No performance decay caused by water freezing was observed, and the water amount in the cell was reduced to an extent by which freeze degradation was avoided. (c) 2006 The Electrochemical Society.

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页码：B11 / B15

页数：5

相关论文

共 15 条

[1] Effects of water removal on the performance degradation of PEMFCs repetitively brought to <0°C [J].

Cho, EA ;

Ko, JJ ;

Ha, HY ;

Hong, SA ;

Lee, KY ;

Lim, TW ;

Oh, IH .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (05) :A661-A665

[2] Characteristics of the PEMFC repetitively brought to temperatures below 0°C [J].

Cho, EA ;

Ko, JJ ;

Ha, HY ;

Hong, SA ;

Lee, KY ;

Lim, TW ;

Oh, IH .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (12) :A1667-A1670

[3] Estimation of size and shape of pores in moist coal utilizing sorbed water as a molecular probe [J].

Hayashi, J ;

Norinaga, K ;

Kudo, N ;

Chiba, T .

ENERGY & FUELS, 2001, 15 (04) :903-909

[4] The design and performance of a PEFC at a temperature below freezing [J].

Hishinuma, Y ;

Chikahisa, T ;

Kagami, F ;

Ogawa, T .

JSME INTERNATIONAL JOURNAL SERIES B-FLUIDS AND THERMAL ENGINEERING, 2004, 47 (02) :235-241

[5] Analysis of PEMFC freeze degradation at-20°C after gas purging [J].

Hou, Junbo ;

Yu, Hongmei ;

Zhang, Shengsheng ;

Sun, Shucheng ;

Wang, Hongwei ;

Yi, Baolian ;

Ming, Pingwen .

JOURNAL OF POWER SOURCES, 2006, 162 (01) :513-520

[6]

LIN Z, 1999, Patent No. 991211005

[7] Low temperature operation and influence parameters on the cold start ability of portable PEMFCs [J].

Oszcipok, M ;

Zedda, M ;

Riemann, D ;

Geckeler, D .

JOURNAL OF POWER SOURCES, 2006, 154 (02) :404-411

[8] Statistic analysis of operational influences on the cold start behaviour of PEM fuel cells [J].

Oszcipok, M ;

Riemann, D ;

Kronenwett, U ;

Kreideweis, M ;

Zedda, A .

JOURNAL OF POWER SOURCES, 2005, 145 (02) :407-415

[9]

OSZCIPOK M, IN PRESS J POWER SOU

[10] Dielectric studies of freezing behavior in porous materials: Water and methanol in activated carbon fibres [J].

Sliwinska-Bartkowiak, M ;

Dudziak, G ;

Sikorski, R ;

Gras, R ;

Gubbins, KE ;

Radhakrishnan, R .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (07) :1179-1184