Novel proton-conducting polymer electrolyte membranes based on PVA/PAMPS/PEG400 blend

被引：31

作者：

Hamaya, Takeo ^{[1
]}

Inoue, Satoko ^{[1
]}

Qiao, Jinli ^{[1
]}

Okada, Tatsuhiro ^{[1
]}

机构：

[1] AIST, Energy Technol Res Inst, Tsukuba, Ibaraki 3058565, Japan

来源：

JOURNAL OF POWER SOURCES | 2006年 / 156卷 / 02期

关键词：

proton conductivity; polymer electrolyte; polyvinyl alcohol; cross-linking; poly-2-acrylamide-2-methyl propane sulfonic acid;

D O I：

10.1016/j.jpowsour.2005.07.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polyvinyl alcohol/poly-2-acrylamide-2-methyl propane sulfonic acid/polyethylene glycol blend membranes were cross-linked by glutaraldehyde in acetone to give water-insoluble film with an excellent ionic conductivity. The water-swelling ratio (WSR) of the membranes was decreased by treating with glutaraldehyde accompanied by increasing proton conductivity. Excellent proton conductivities (0.02-0.083 S cm(-1)) were obtained for the resulted cross-linked blend membranes. Methanol permeability of the cross-linked film was significantly low, around one-fifth as low as that of Nation. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：311 / 314

页数：4

共 25 条

[1] Elaboration and study of a PANI/PAMPS/WO3 all solid-state electrochromic device [J].

Bernard, MC ;

Hugot-Le Goff, A ;

Zeng, W .

ELECTROCHIMICA ACTA, 1998, 44 (05) :781-796

[2] Synthesis and characterization of proton-conducting copolymers on the basis of vinylpyrrolidone and acrylamido sulfonic acid [J].

Bozkurt, A ;

Ekinci, Ö ;

Meyer, WH .

JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 90 (12) :3347-3353

[3] A POLYMERIC SOLID-STATE ELECTROCHROMIC CELL [J].

CALVERT, JM ;

MANUCCIA, TJ ;

NOWAK, RJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (05) :951-953

[4] SEPARATION OF LIQUID-MIXTURES BY USING POLYMER MEMBRANES .1. WATER ALCOHOL SEPARATION BY PERVAPORATION THROUGH PVA-G-MMA MA MEMBRANE [J].

CHIANG, WY ;

HU, CM .

JOURNAL OF APPLIED POLYMER SCIENCE, 1991, 43 (11) :2005-2012

[5] PAMPSA-IM based proton conducting polymer electrolytes [J].

Erdemi, H ;

Bozkurt, A ;

Meyer, WH .

SYNTHETIC METALS, 2004, 143 (01) :133-138

[6]

HAMNETT A, 2003, HDB FUEL CELLS FUNDA, V1, P305

[7] TUNGSTEN-OXIDE PRUSSIAN BLUE ELECTROCHROMIC SYSTEM BASED ON A PROTON-CONDUCTING POLYMER ELECTROLYTE [J].

HO, KC ;

RUKAVINA, TG ;

GREENBERG, CB .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (08) :2061-2067

[8] POLY(VINYL ALCOHOL) GEL SUBLAYERS FOR REVERSE-OSMOSIS MEMBRANES .1. INSOLUBILIZATION BY ACID-CATALYZED DEHYDRATION [J].

IMMELMAN, E ;

SANDERSON, RD ;

JACOBS, EP ;

VANREENEN, AJ .

JOURNAL OF APPLIED POLYMER SCIENCE, 1993, 50 (06) :1013-1034

[9] Water-swollen cation-exchange membranes prepared using poly(vinyl alcohol) (PVA)/poly(styrene sulfonic acid-co-maleic acid) (PSSA-MA) [J].

Kang, MS ;

Choi, YJ ;

Moon, SH .

JOURNAL OF MEMBRANE SCIENCE, 2002, 207 (02) :157-170

[10] Characterization of poly(vinyl alcohol)/poly(ethylene glycol) hydrogels and PVA-derived hybrids by small-angle X-ray scattering and FTIR spectroscopy [J].

Mansur, HS ;

Oréfice, RL ;

Mansur, AAP .

POLYMER, 2004, 45 (21) :7193-7202

← 1 2 3 →