Effect of visible light on the water contact angles on illuminated oxide semiconductors other than TiO2

被引:47
作者
Rico, V. [1 ]
Lopez, C. [1 ]
Borras, A. [1 ]
Espinos, J. P. [1 ]
Gonzalez-Elipe, A. R. [1 ]
机构
[1] Univ Seville, CSIC, Inst Ciencia Mat Sevilla, Seville 41092, Spain
关键词
wetting; oxide semiconductors; visible light irradiation;
D O I
10.1016/j.solmat.2006.05.005
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Wide band gap semiconductor oxides such as TiO2, Ta2O5, ZnO, indium-tin oxide, InTaO4 or In2O3 are materials with water contact angles in dark between 60 degrees and 130 degrees. The present investigation shows that thin films of these oxides become hydrophilic when they are irradiated with ultraviolet light. This finding indicates that the transformation of the wetting properties of illuminated wide band gap oxides is a common phenomenon not restricted to TiO2. An additional evidence found for ZnO and InTaO4 is that the water contact angle decreases by 30 degrees/40 degrees when they are irradiated with visible light. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:2944 / 2949
页数:6
相关论文
共 21 条
[1]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[2]   Self-cleaning surfaces - virtual realities [J].
Blossey, R .
NATURE MATERIALS, 2003, 2 (05) :301-306
[3]   Tantalum pentoxide (Ta2O5) thin films for advanced dielectric applications [J].
Chaneliere, C ;
Autran, JL ;
Devine, RAB ;
Balland, B .
MATERIALS SCIENCE & ENGINEERING R-REPORTS, 1998, 22 (06) :269-322
[4]   Photoelectron spectroscopic investigation of nitrogen-doped titania nanoparticles [J].
Chen, XB ;
Burda, C .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (40) :15446-15449
[5]  
FUJISHIMA A, 1999, TIO2 PHOTOCATALYST F
[6]   Photoefficiency and optical, microstructural, and structural properties of TiO2 thin films used as photoanodes [J].
Gracia, F ;
Holgado, JP ;
González-Elipe, AR .
LANGMUIR, 2004, 20 (05) :1688-1697
[7]   Recent advances in ZnO materials and devices [J].
Look, DC .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2001, 80 (1-3) :383-387
[8]   Preparation of transparent and conductive Al-doped ZnO thin films by ECR plasma enhanced CVD [J].
Martín, A ;
Espinós, JP ;
Justo, A ;
Holgado, JP ;
Yubero, F ;
González-Elipe, AR .
SURFACE & COATINGS TECHNOLOGY, 2002, 151 :289-293
[9]   Photoinduced hydrophilicity of heteroepitaxially grown ZnO thin films [J].
Miyauchi, M ;
Shimai, A ;
Tsuru, Y .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (27) :13307-13311
[10]   Photocatalysis and photoinduced hydrophilicity of various metal oxide thin films [J].
Miyauchi, M ;
Nakajima, A ;
Watanabe, T ;
Hashimoto, K .
CHEMISTRY OF MATERIALS, 2002, 14 (06) :2812-2816