Supramolecular assembly: A comparative structural study of the incorporation of bis(2-guanidinobenzimidazolo)nickel(II) into supramolecular arrays

被引：12

作者：

Bishop, MM

Lindoy, LF ^{[1
]}

Turner, P

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[2] Sydney Grammar Sch, Darlinghurst, NSW 2010, Australia

来源：

SUPRAMOLECULAR CHEMISTRY | 2002年 / 14卷 / 2-3期

关键词：

X-ray crystallography; diffraction; hydrogen bond; nickel C4; crystal engineering; supramolecular chemistry;

D O I：

10.1080/10610270290026086

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structural effects of incorporating a non-planar neutral metal complex, bis(2-guanidinobenzimidazolo)nickel(II), into three supramolecular arrays are described. The complex has a donor-acceptor-donor (DAD) hydrogen bonding motif on each ligand and this motif is used to link it to bis(biureto)nickelate(II) ions, or to 1,8-naphthalimide or phthalimide molecules, all of which incorporate a complementary acceptor-donor-acceptor (ADA) hydrogen bonding motif. The geometry about the metal ion as well as the nature of the network of hydrogen bonds formed have significant influences on the supramolecular structure adopted. An interesting combination of intramolecular hydrogen bonding and close pi-stacking interactions also occur in each species.

引用

页码：179 / 188

页数：10

共 24 条

[1] COMPLETION AND REFINEMENT OF CRYSTAL-STRUCTURES WITH SIR92 [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, C ;

GUAGLIARDI, A .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 (pt 3) :343-350

[2]

AndradeLopez N, 1997, HETEROATOM CHEM, V8, P397, DOI 10.1002/(SICI)1098-1071(1997)8:5<397::AID-HC4>3.0.CO

[3]

2-6

[4] Coordination behaviour of 2-guanidinobenzimidazole towards cobalt(II), nickel(II), copper(II) and zinc(II). An experimental and theoretical study [J].

BarbaBehrens, N ;

VazquezOlmos, A ;

CastilloBlum, SE ;

Hojer, G ;

MezaHojer, S ;

Hernandez, RM ;

RosalesHoz, MD ;

Vicente, R ;

Escuer, A .

TRANSITION METAL CHEMISTRY, 1996, 21 (01) :31-37

[5] Proton controlled supramolecular assembly: A comparative structural study of bis(2-guanidinobenzimidazolo)nickel(II) with bis(2-guanidinobenzimidazole)nickel(II) nitrate and 2-guanidinobenzimidazole [J].

Bishop, MM ;

Lindoy, LF ;

Skelton, BW ;

White, A .

SUPRAMOLECULAR CHEMISTRY, 2001, 13 (02) :293-301

[6]

BISHOP MM, 2002, IN PRESS J CHEM SOC

[7]

BISHOP MM, 2001, IN PRESS J HETEROCYC

[8] AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY [J].

BLESSING, RH .

ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :33-38

[9]

*BRUK SMART SAINT, 1995, AR DET CONTR DAT INT

[10]

HALL SR, 1999, XTAL3 6 SYSTEM

← 1 2 3 →