A very large Rh-Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

被引：70

作者：

Coppens, P ^{[1
]}

Gerlits, O

Vorontsov, II

Kovalevsky, AY

Chen, YS

Graber, T

Gembicky, M

Novozhilova, IV

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

[2] Univ Toledo, Toledo, OH 43606 USA

[3] Univ Chicago, Chicago, IL 60637 USA

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 19期

关键词：

D O I：

10.1039/b409463h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A very large Rh - Rh contraction of similar to0.85 Angstrom occurs on excitation of the [Rh-2(1,8-diisocyano-p-menthane)(4)](2+) ion to its triplet state.

引用

页码：2144 / 2145

页数：2

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