Electron tunneling in conductor-insulator composites with spherical fillers

被引:31
作者
Ambrosetti, G. [1 ,2 ]
Johner, N. [1 ]
Grimaldi, C. [1 ]
Maeder, T. [1 ]
Ryser, P. [1 ]
Danani, A. [2 ]
机构
[1] Ecole Polytech Fed Lausanne, LPM, CH-1015 Lausanne, Switzerland
[2] Univ Appl Sci So Switzerland, ICIMSI, CH-6928 Manno, Switzerland
关键词
carbon; composite materials; electrical conductivity; filled polymers; Monte Carlo methods; tunnelling; BLACK POLYMER COMPOSITES; PERCOLATION-THRESHOLD; CARBON; SUPERLOCALIZATION; NETWORK;
D O I
10.1063/1.3159040
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report on our Monte Carlo calculations of the conductivity of monosized and conducting spherical particles dispersed in a homogeneous matrix, with interparticle transport mechanism given by electron tunneling. We show that our numerical results can be reproduced by a simple formula based on a critical path analysis and which gives also a practical way to estimate the characteristic tunneling length xi in real composites. We find that xi is about 1 nm for several low structure carbon black polymer composites, in agreement with the expected order of magnitude.
引用
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页数:3
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