C-3-symmetric chiral amidate complexes: Effects of ligand binding on cavity structure

被引：51

作者：

Hammes, BS

RamosMaldonado, D

Yap, GPA

LiableSands, L

Rheingold, AL

Young, VG

Borovik, AS

机构：

[1] KANSAS STATE UNIV,DEPT CHEM,MANHATTAN,KS 66506

[2] UNIV DELAWARE,NEWARK,DE 19716

[3] UNIV MINNESOTA,MINNEAPOLIS,MN 55455

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 15期

关键词：

D O I：

10.1021/ic970124l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new homochiral tripodal ligand tris(N-(S)-(-)-(alpha)-methylbenzylcarbomoylmethyl)amine (H(3)1(S-mbz)) is reported, along with the preparation and structural characterization of two metal complexes K[Zn1(S-mbz)] and K[Fe1(S-mbz)(NO)]. Significant changes in cavity structure are observed upon binding external ligands.

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页码：3210 / &

页数：3

相关论文

共 18 条

[1] A TRIPOD LIGAND WITH 3 DIFFERENT LEGS AND SOME CHIRAL ZINC-COMPLEXES THEREOF [J].

ABUFARAG, A ;

VAHRENKAMP, H .

INORGANIC CHEMISTRY, 1995, 34 (12) :3279-3284

[2] ENANTIOMERICALLY PURE C3-SYMMETRICAL TRIPODAL PYRIDINE LIGANDS [J].

ADOLFSSON, H ;

WARNMARK, K ;

MOBERG, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (15) :1054-1055

[3] NEW CHIRAL C3-SYMMETRICAL TRIPODAL PHOSPHANES [J].

BURK, MJ ;

HARLOW, RL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (12) :1462-1464

[4] CONFORMATIONALLY DRIVEN, PROPELLER-LIKE CHIRALITY IN LABILE COORDINATION-COMPLEXES [J].

CANARY, JW ;

ALLEN, CS ;

CASTAGNETTO, JM ;

WANG, YH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (32) :8484-8485

[5]

CHELUCCI G, 1992, GAZZ CHIM ITAL, V122, P89

[6] MODEL STUDIES OF ALPHA-KETO ACID-DEPENDENT NONHEME IRON ENZYMES - NITRIC-OXIDE ADDUCTS OF [FE-II(L)(O(2)CCOPH)](CLO4) COMPLEXES [J].

CHIOU, YM ;

QUE, L .

INORGANIC CHEMISTRY, 1995, 34 (12) :3270-3278

[7] PRINCIPLES OF STRUCTURE, BONDING, AND REACTIVITY FOR METAL NITROSYL COMPLEXES [J].

ENEMARK, JH ;

FELTHAM, RD .

COORDINATION CHEMISTRY REVIEWS, 1974, 13 (04) :339-406

[8]

Feltham R.D., 1981, TOPICS INORGANIC ORG, V12, P155

[9] COORDINATION CHEMISTRY WITH STERICALLY HINDERED HYDROTRIS(PYRAZOLYL)BORATE LIGANDS - ORGANOMETALLIC AND BIOINORGANIC PERSPECTIVES [J].

KITAJIMA, N ;

TOLMAN, WB .

PROGRESS IN INORGANIC CHEMISTRY, VOL 43, 1995, 43 :419-531

[10] OPTICALLY-ACTIVE AND C3-SYMMETRICAL TRIS(PYRAZOLYL)HYDROBORATE AND TRIS(PYRAZOLYL)PHOSPHINE OXIDE LIGANDS - SYNTHESIS AND STRUCTURAL CHARACTERIZATION [J].

LECLOUX, DD ;

TOKAR, CJ ;

OSAWA, M ;

HOUSER, RP ;

KEYES, MC ;

TOLMAN, WB .

ORGANOMETALLICS, 1994, 13 (07) :2855-2866