Synthesis and crystal structure of dimeric 2,4,6-triphenylphenylbismuthdichloride

被引：16

作者：

Avtomonov, EV ^{[1
]}

Li, XW ^{[1
]}

Lorberth, J ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 530卷 / 1-2期

关键词：

bismuth; arylbismuth compounds; X-ray diffraction;

D O I：

10.1016/S0022-328X(96)06501-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of BiCl3 with one equivalent of 2,4,6-triphenylphenyllithium in toluene results in the formation of crystalline 2,4,6-triphenyl-phenylbismuthdichloride toluene disolvate (1). The crystal structure of 1 has been determined by X-ray diffraction. In spite of the extremely bulky substituents at the bismuth atom, complex 1 is dimeric in the solid state with intramolecular Bi-CI bond lengths of 2.530(1)Angstrom and bridging Bi-Cl of 3.074(1)Angstrom.

引用

页码：71 / 74

页数：4

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