Reaction of 3-alkenols with thallium trinitrate: An unexpected and useful ring contraction

被引：11

作者：

Ferraz, HMC ^{[1
]}

Santos, AP ^{[1
]}

Silva, LF ^{[1
]}

Vieira, TD ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05599970 Sao Paulo, Brazil

来源：

SYNTHETIC COMMUNICATIONS | 2000年 / 30卷 / 04期

基金：

巴西圣保罗研究基金会;

关键词：

D O I：

10.1080/00397910008087377

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first thallium trinitrate (TTN) mediated ring contraction of cyclic homoallylic alcohols, using a 1:1 mixture of AcOH and H2O as solvent, is described. The reaction or two of these alcohols with excess of TTN in pentane gave alpha-spirocyclopentyl-gamma-butirolactones in reasonable yields.

引用

页码：751 / 762

页数：12

共 17 条

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