Structural aspects related to the ion exchange process in layered niobate K4Nb6O17

被引：6

作者：

Bizeto, Marcos A. ^{[1
]}

Christino, Fernando P. ^{[1
]}

Tavares, Marina F. M. ^{[1
]}

Constantino, Vera R. L. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, Brazil

来源：

QUIMICA NOVA | 2006年 / 29卷 / 06期

关键词：

K4Nb6O17; ion exchange; intercalation;

D O I：

10.1590/S0100-40422006000600013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The niobate, with formula KNb 6017 has a layered structure formed by stacked negative sheets and exchangeable cations in the interlayer region. In this study we discuss some structural aspects related to the ion exchange in layered hexamobate based on X-ray diffiractometry and vibrational Raman spectroscopy data. Hexamobate has two distinct interlayer regions and the potassium ions of one interlayer in particular are preferably exchanged by other cations, leading to an interstratified material.

引用

页码：1215 / 1220

页数：6

共 32 条

[1] Preparation of ion-exchangeable thin films of layered niobate K4Nb6O17 [J].

Abe, R ;

Hara, M ;

Kondo, JN ;

Domen, K ;

Shinohara, K ;

Tanaka, A .

CHEMISTRY OF MATERIALS, 1998, 10 (06) :1647-1651

[2] Preparation of porous niobium oxide by the exfoliation of K4Nb6O17 and its photocatalytic activity [J].

Abe, R ;

Shinohara, K ;

Tanaka, A ;

Hara, M ;

Kondo, JN ;

Domen, K .

JOURNAL OF MATERIALS RESEARCH, 1998, 13 (04) :861-865

[3] Preparation of porous niobium oxides by soft-chemical process and their photocatalytic activity [J].

Abe, R ;

Shinohara, K ;

Tanaka, A ;

Hara, M ;

Kondo, JN ;

Domen, K .

CHEMISTRY OF MATERIALS, 1997, 9 (10) :2179-2184

[4]

ALBERTI G, 1996, SOLID STATE SUPRAMOL, V7

[5] Porphyrin inclusion into hexaniobate nanoscrolls [J].

Bizeto, MA ;

Constantino, VRL .

MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 83 (1-3) :212-218

[6] Organic-inorganic hybrid material synthesized by porphyrin intercalation into a layered niobate host matrix [J].

Bizeto, MA ;

De Faria, DLA ;

Constantino, VRL .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1999, 18 (08) :643-646

[7] Layered H2K2Nb6O17 exfoliation promoted by n-butylamine [J].

Bizeto, MA ;

Constantino, VRL .

MATERIALS RESEARCH BULLETIN, 2004, 39 (12) :1811-1820

[8] Structural aspects and thermal behavior of the proton-exchanged layered niobate K4Nb6O17 [J].

Bizeto, MA ;

Constantino, VRL .

MATERIALS RESEARCH BULLETIN, 2004, 39 (11) :1729-1736

[9]

BRINDLEY GW, 1984, CRYSTAL STRUCTURES C, pCH4

[10]

Carrado K.A., 2004, HDB LAYERED MAT

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