Supercritical hydrogenation and acid-catalysed reactions "without gases"

被引：50

作者：

Hyde, JR ^{[1
]}

Poliakoff, M ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 13期

关键词：

D O I：

10.1039/b404181j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The high temperature catalytic decomposition of HCO2H and HCO2Et are used to generate the high pressure H-2 and the supercritical fluids needed for micro-scale hydrogenation of organic compounds; our approach overcomes the problems and limitations of handling high pressure gases on a small-scale and opens the way to the widespread use of continuous supercritical reactions in the laboratory.

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页码：1482 / 1483

页数：2

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