Aziridination of conjugated nitroalkenes

被引：14

作者：

Fioravanti, S ^{[1
]}

Pellacani, L ^{[1
]}

Stabile, S ^{[1
]}

Tardella, PA ^{[1
]}

Ballini, R ^{[1
]}

机构：

[1] UNIV CAMERINO,DIPARTIMENTO SCI CHIM,I-62032 CAMERINO,ITALY

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(97)00593-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The recently proposed amination methodology based on solid bases induced decomposition of arenesulphonyloxycarbamates (ArSO3NHCO2Et) has been applied to alpha-nitroalkenes. alpha-nitroaziridines have been obtained in high yields and purity, under mild conditions. (C) 1997 Elsevier Science Ltd.

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收藏

页码：3309 / 3310

页数：2

相关论文

共 17 条

[1]

[Anonymous], J MOL STRUCT THEOCHE

[2] CHEMOSELECTIVE SYNTHESIS OF FUNCTIONALIZED CONJUGATED NITROALKENES [J].

BALLINI, R ;

CASTAGNANI, R ;

PETRINI, M .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (07) :2160-2162

[3] A NEW, HIGHLY EFFICIENT SYNTHESIS OF CONJUGATED NITROCYCLOALKENES [J].

BALLINI, R ;

PALESTINI, C .

TETRAHEDRON LETTERS, 1994, 35 (31) :5731-5734

[4] CS2CO3 OR CAO AS PROMOTERS OF ETHYL N-([(4-METHYLPHENYL)SULPHONYL]OXY)CARBAMATE IN AMINATION REACTIONS [J].

BARANI, M ;

FIORAVANTI, S ;

PELLACANI, L ;

TARDELLA, PA .

TETRAHEDRON, 1994, 50 (38) :11235-11238

[5] CONJUGATED NITROALKENES - VERSATILE INTERMEDIATES IN ORGANIC-SYNTHESIS [J].

BARRETT, AGM ;

GRABOSKI, GG .

CHEMICAL REVIEWS, 1986, 86 (05) :751-762

[6] HETEROSUBSTITUTED NITROALKENES IN SYNTHESIS [J].

BARRETT, AGM .

CHEMICAL SOCIETY REVIEWS, 1991, 20 (01) :95-127

[7] Aziridination of alpha,beta-unsaturated esters by (ethoxycarbonyl)nitrene [J].

Carducci, M ;

Fioravanti, S ;

Loreto, MA ;

Pellacani, L ;

Tardella, PA .

TETRAHEDRON LETTERS, 1996, 37 (21) :3777-3778

[8]

ENDERS D, 1995, ANGEW CHEM INT EDIT, V34, P455, DOI 10.1002/anie.199504551

[9]

Enders D, 1996, SYNTHESIS-STUTTGART, P1443

[10]

Enders D., 1995, ANGEW CHEM, V107, P527