Self-assembly directed by NH-O hydrogen bonding: A neutron study of a trilayered supramolecular array formed between 1,2-diaminoethane and benzoic acid

被引:12
作者
Adam, KR
Atkinson, IM
Davis, RL
Lindoy, LF
Mahinay, MS
McCool, BJ
Skelton, BW
White, AH
机构
[1] AUSTRALIAN NUCL SCI & TECHNOL ORG, MENAI, NSW 2234, AUSTRALIA
[2] UNIV SYDNEY, SCH CHEM, SYDNEY, NSW 1006, AUSTRALIA
[3] UNIV WESTERN AUSTRALIA, DEPT CHEM, NEDLANDS, WA 6009, AUSTRALIA
关键词
D O I
10.1039/a605748i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The supramolecular array formed by co-crystallisation of 1,2-diaminoethane and benzoic acid is investigated by neutron diffraction; the system self-assembles into an unusual layered structure composed of two-dimensional hydrogen-bonded networks sandwiched between layers of edge-to-face stacked aromatic systems; the number of hydrogen-bond donors and accepters is balanced in the structure.
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页码:467 / 468
页数:2
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