Selective room temperature hydrogenolysis of aromatic fluorocarbons mediated by a low-valent zirconium complex

被引：53

作者：

Kiplinger, JL ^{[1
]}

Richmond, TG ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 10期

关键词：

D O I：

10.1039/cc9960001115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of fluorinated aromatic compounds with (C5H5)(2)ZrCl2, HgCl2, Mg or (C5H5)(2)ZrCl2, PMe(3), Mg results in selective room temperature hydrogenolysis of aromatic C-F bonds.

引用

页码：1115 / 1116

页数：2

共 17 条

[1] CATALYTIC ACTIVATION OF CARBON-FLUORINE BONDS BY A SOLUBLE TRANSITION-METAL COMPLEX [J].

AIZENBERG, M ;

MILSTEIN, D .

SCIENCE, 1994, 265 (5170) :359-361

[2]

AIZXENBERG M, 1995, J AM CHEM SOC, V117, P8674

[3] NUCLEOPHILIC DISPLACEMENT IN POLYHALOGENOAROMATIC COMPOUNDS .13. POLYFLUOROARENE SYSTEMS [J].

ATWAL, RK ;

BOLTON, R .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1987, 40 (02) :241-247

[4]

Banks R.E., 1994, ORGANOFLUORINE CHEM

[5] COBALTOCENIUM FLUORIDE - A NOVEL SOURCE OF NAKED FLUORIDE FORMED BY CARBON FLUORINE BOND ACTIVATION IN A SATURATED PERFLUOROCARBON [J].

BENNETT, BK ;

HARRISON, RG ;

RICHMOND, TG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (24) :11165-11166

[6] NUCLEOPHILIC DISPLACEMENT IN POLYHALOGENOAROMATIC COMPOUNDS .8. KINETICS OF METHOXYDEFLUORINATION OF SOME POLYFLUORONAPHTHALENES [J].

BOLTON, R ;

SANDALL, JPB .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1978, (08) :746-750

[7] NEW REACTION OF SATURATED FLUOROCARBONS - PARTIAL REDUCTION BY NH3 WITH HG PHOTOSENSITIZATION [J].

BURDENIUC, J ;

CHUPKA, W ;

CRABTREE, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (40) :10119-10120

[8]

Dungan CH, 1970, COMPILATION REPORTED

[9] REACTIONS OF AROMATIC FLUOROCARBONS WITH HYDROGEN [J].

FLORIN, RE ;

PUMMER, WJ ;

WALL, LA .

JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1959, 62 (03) :119-122

[10]

HUDLICKY M, 1995, ACS MONOGRAPH, V187

← 1 2 →