Porphyrin-Incorporated 2D D-A Polymers with Over 8.5% Polymer Solar Cell Efficiency

被引：111

作者：

Chao, YI-Hsiang ^{[1
]}

Jheng, Jyun-Fong ^{[1
]}

Wu, Jhong-Sian ^{[1
]}

Wu, Kuan-Yi ^{[1
]}

Peng, Hsih-Hao ^{[1
]}

Tsai, Ming-Chi ^{[2
]}

Wang, Chin-Li ^{[1
,2
]}

Hsiao, Yen-Ni ^{[2
]}

Wang, Chien-Lung

Lin, Ching-Yao ^{[2
]}

Hsu, Chain-Shu ^{[1
]}

机构：

[1] Natl Chiao Tung Univ, Dept Appl Chem, 1001 Ta Hsueh Rd, Hsinchu 30010, Taiwan

[2] Natl Chi Nan Univ, Dept Appl Chem, Puli 54561, Nantou, Taiwan

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 30期

关键词：

HIGHLY EFFICIENT; CONJUGATED POLYMERS; PERFORMANCE; COPOLYMERS; ACCEPTOR; DESIGN; DONOR; BENZOTHIADIAZOLE; FULLERENES; CRYSTALS;

D O I：

10.1002/adma.201401345

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A copolymerization strategy is developed to utilize porphyrin as a complementary light-harvesting unit (LHU) in D-A polymers. For polymer solar cells (PSCs), the presence of LHUs increases the short-circuit current density (Jsc) without sacrificing the open-circuit voltage (Voc) and fill factor (FF). Up to 8.0% power conversion efficiency (PCE) is delivered by PPor-2:PC71BM single-junction PSCs. A PCE of 8.6% is achieved when a C-PCBSD cathodic interlayer is introduced. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5205 / 5210

页数：6

共 48 条

[1] Dithienogermole As a Fused Electron Donor in Bulk Heterojunction Solar Cells [J].

Amb, Chad M. ;

Chen, Song ;

Graham, Kenneth R. ;

Subbiah, Jegadesan ;

Small, Cephas E. ;

So, Franky ;

Reynolds, John R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (26) :10062-10065

[2] A strategy to design highly efficient porphyrin sensitizers for dye-sensitized solar cells [J].

Chang, Yu-Cheng ;

Wang, Chin-Li ;

Pan, Tsung-Yu ;

Hong, Shang-Hao ;

Lan, Chi-Ming ;

Kuo, Hshin-Hui ;

Lo, Chen-Fu ;

Hsu, Hung-Yu ;

Lin, Ching-Yao ;

Diau, Eric Wei-Guang .

CHEMICAL COMMUNICATIONS, 2011, 47 (31) :8910-8912

[3] Solution-Processed (Graphene Oxide)-(d0 Transition Metal Oxide) Composite Anodic Buffer Layers toward High-Performance and Durable Inverted Polymer Solar Cells [J].

Chao, Yi-Hsiang ;

Wu, Jhong-Sian ;

Wu, Chen-En ;

Jheng, Jyun-Fong ;

Wang, Chien-Lung ;

Hsu, Chain-Shu .

ADVANCED ENERGY MATERIALS, 2013, 3 (10) :1279-1285

[4] Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].

Cheng, Yen-Ju ;

Yang, Sheng-Hsiung ;

Hsu, Chain-Shu .

CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923

[5] Synthesis of 5H-Dithieno[3,2-b:2′,3′-d]pyran as an Electron-Rich Building Block for Donor-Acceptor Type Low-Bandgap Polymers [J].

Dou, Letian ;

Chen, Chun-Chao ;

Yoshimura, Ken ;

Ohya, Kenichiro ;

Chang, Wei-Hsuan ;

Gao, Jing ;

Liu, Yongsheng ;

Richard, Eric ;

Yang, Yang .

MACROMOLECULES, 2013, 46 (09) :3384-3390

[6] π-Conjugated Polymers for Organic Electronics and Photovoltaic Cell Applications [J].

Facchetti, Antonio .

CHEMISTRY OF MATERIALS, 2011, 23 (03) :733-758

[7] SPECTRA OF PORPHYRINS [J].

GOUTERMAN, M .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1961, 6 (01) :138-&

[8]

Guo XG, 2013, NAT PHOTONICS, V7, P825, DOI [10.1038/NPHOTON.2013.207, 10.1038/nphoton.2013.207]

[9] Segregated Donor-Acceptor Columns in Liquid Crystals That Exhibit Highly Efficient Ambipolar Charge Transport [J].

Hayashi, Hironobu ;

Nihashi, Wataru ;

Umeyama, Tomokazu ;

Matano, Yoshihiro ;

Seki, Shu ;

Shimizu, Yo ;

Imahori, Hiroshi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (28) :10736-10739

[10] How Far Can Polymer Solar Cells Go? In Need of a Synergistic Approach [J].

He, Feng ;

Yu, Luping .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2011, 2 (24) :3102-3113

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