The total synthesis of (±)-arisugacin A

被引：18

作者：

Cole, KP ^{[1
]}

Hsung, RP ^{[1
]}

Yang, XF ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(02)00551-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A 20-step total synthesis of (+/-)-arisugacin A with an overall yield of 2.1% is described here. This synthesis features highly convergent formal [3 + 3] cycloaddition and a strategic dihydroxylation-deoxygenation protocol leading to the desired angular C12a-OH. (C) 2002 Elsevier Science Ltd. All rights reserved.

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收藏

页码：3341 / 3345

页数：5

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