Application of Redox Non-Innocent Ligands to Non-Aqueous Flow Battery Electrolytes

被引：93

作者：

Cappillino, Patrick J. ^{[1
]}

Pratt, Harry D., III ^{[2
]}

Hudak, Nicholas S. ^{[2
]}

Tomson, Neil C. ^{[3
]}

Anderson, Travis M. ^{[2
]}

Anstey, Mitchell R. ^{[1
]}

机构：

[1] Sandia Natl Labs, Livermore, CA 94551 USA

[2] Sandia Natl Labs, Albuquerque, NM 87185 USA

[3] St Johns Univ, Dept Chem, Coll St Benedict, St Joseph, MN 56374 USA

来源：

ADVANCED ENERGY MATERIALS | 2014年 / 4卷 / 01期

关键词：

COMPLEXES; GRAPHITE; BEHAVIOR; MEMBRANE; PROGRESS; STORAGE; ION;

D O I：

10.1002/aenm.201300566

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

High energy-density, redox flow batteries (RFB) can provide cost-effective, grid-scale energy storage, facilitating the use of intermittent sources such as solar and wind power. A new electrolyte based on vanadium and redox-active ligands that stores equivalents of charge separately from the metal center is presented. Electrolytes composed of non-innocent ligands greatly enhance both the energy density and stability of non-aqueous RFBs © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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页数：4

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