Radiation dynamics of post-breakdown laser induced plasma

被引:72
作者
Gornushkin, IB
Kazakov, AY
Omenetto, N
Smith, BW
Winefordner, JD
机构
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[2] State Univ Aerosp Instrumentat, Dept Math, St Petersburg 190000, Russia
关键词
laser induced plasma; LIBS; radiative plasma model; radiative transfer;
D O I
10.1016/j.sab.2003.12.023
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
A radiation dynamic model is developed for a post-breakdown stage of a laser induced plasma expanding into vacuum. The model describes the plasma formed on a small solid particle, which is completely vaporized by a laser. The symmetry of the expanding plasma is spherical. The time frame for the applicability of the model is somewhat between a hundreds of nanoseconds, after the laser pulse is terminated, and a few microseconds, when the plasma ceases to emit. The model is based on a system of gas dynamic equations coupled with the equation of radiative transfer. Local thermodynamic equilibrium is assumed, allowing the application of the collision-dominated plasma model as well as standard statistical distributions. Calculations are performed for a dual SiC system, although calculations for any arbitrary number of system's components are permitted. The model has two implications. First, an analytical expression for the plasma radiation dynamics is obtained by artificially setting the initial conditions. Second, from experimentally measured plasma parameters, information is deduced about the initial state of the plasma. The main model input parameters are the total number and distribution of plasma species and the initial distribution of temperature. Some of the other model inputs, such as the speed of the plasma front and the temperature profile across the plasma can be directly measured, thus providing valuable experimental feedback to the model. The model outputs are the evolution of plasma temperature, the spatial and temporal distributions of atoms, ions and electron number densities and the evolution of the plasma spectrum in a desirable spectral window (e.g. 280-290 nm for the chosen in this work SiC system). (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:401 / 418
页数:18
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