Synthesis of 2-acrylamido-2-methylpropanoic acid and its copolymerization with acrylamide

被引：2

作者：

Camail, M ^{[1
]}

Margaillan, A ^{[1
]}

Thuret, S ^{[1
]}

Vernet, JL ^{[1
]}

机构：

[1] UNIV TOULON & VAR,LAB CHIM APPL,EQUIPE ACCUEIL MAT FINAL SPECIF,F-83957 LA GARDE,FRANCE

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1996年 / 197卷 / 08期

关键词：

D O I：

10.1002/macp.1996.021970821

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];

摘要：

The synthesis of 2-acrylamido-2-methylpropanoic acid (2A2MPA) was carried out starting from 2-methylpropanoic acid. Copolymerizations of the 2A2MPA salt (2A2MPANa, monomer A) with acrylamide (AM, monomer B) were investigated using K2S2O8 as initiator. They were terminated before reaching 15% conversion. A range of feed compositions was selected (2A2MPANa increasing from 10 to 100 mol-%) and the compositions of the copolymers obtained were assessed through C-13 NMR. The reactivity ratios for the couple A, B were determined as r(A) = 0,76 and r(B) = 1,06. One additional copolymerization was allowed to reach 100% conversion, and the final copolymer showed interesting drag reduction properties.

引用

页码：2595 / 2602

页数：8

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