Highly ordered functional organosilicas by template-directed hydrolysis-polycondensation of chiral camphorsulfonamide precursors

被引：35

作者：

Gadenne, Benoit ^{[1
]}

Hesemann, Peter ^{[1
]}

Polshettiwar, Vivek ^{[1
]}

Moreau, Joel J. E. ^{[1
]}

机构：

[1] Ecole Natl Super Chim Montpellier, UMR CNRS 5076, F-34296 Montpellier 05, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 18期

关键词：

mesoporous materials; organic-inorganic hybrid composites; sol-gel processes; supported catalysts; template synthesis;

D O I：

10.1002/ejic.200600287

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trialkoxysilylated camphorsulfonamides have been used for the synthesis of functional orgariosilicas in a template-directed hydrolysis-polycondensation with tetraethylorthosilicate (TEOS). The sol-gel transformation leading to the formation of highly ordered materials indicates that trialkoxysilylated camphorsulfonamides allow the synthesis of functional organosilicas with high structural regularity. This behaviour arises from the affinity of the chiral precursors towards the lyotropic phase of the ionic surfactants in the aqueous hydrolysis-polycondensation mixture.

引用

页码：3697 / 3702

页数：6

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