Strontium ferrite nanoparticles synthesized in presence of polyvinylalcohol:: Phase composition, microstructural and magnetic properties

Systematic study was devoted to the synthesis of hexagonal strontium ferrite nanoparticles employing polyvinylalcohol as stabilizing agent. Preliminary experiments allowed to select an optimal sol having molar ratio Sr2+/Fe3+ = 12, weight ratio PVA/[Sr2+ + Fe3+]= 1.4 and pH = 2.1. The obtained sol were transformed to gels by an evaporation of water at 100 degrees C and drying at 112 degrees C under vacuum. The subsequent calcination was carried out for 3 h at 400 C, achieved by heating rate of 17 K/min. The obtained precursor was used for a detail study of influence of annealing conditions (temperature range 600-700 degrees C, annealing time 10-190 min) on the resulting properties. Semiquantitative X-ray phase analysis approved a gradual increase of the M-phase content and a gradual growth of M-phase crystallites with temperature and time. Magnetic measurements showed a distinct influence of the phase composition, namely ratio of the contents of M-phase and maghemite on the shape of the magnetic loops, while the crystallite sizes have only a slight effect. (c) 2006 Elsevier B.V. All rights reserved.