Reactions on a solid surface. A simple, economical and efficient Friedel-Crafts acylation reaction over zinc oxide (ZnO) as a new catalyst

被引:212
作者
Sarvari, MH [1 ]
Sharghi, H [1 ]
机构
[1] Shiraz Univ, Fac Sci, Dept Chem, Shiraz 71454, Iran
关键词
D O I
10.1021/jo0494477
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Zinc oxide (ZnO) brings about a rapid Friedel-Crafts acylation of a range of activated and unactivated aromatic compounds such as anisole and chlorobenzene with acid chlorides in solvent-free conditions at room temperature. The ZnO powder can be reused up to three times after simple washing with dichloromethane.
引用
收藏
页码:6953 / 6956
页数:4
相关论文
共 27 条
[1]   LiClO4-acyl anhydrides complexes as powerful acylating reagents of aromatic compounds in solvent free conditions [J].
Bartoli, G ;
Bosco, M ;
Marcantoni, E ;
Massaccesi, M ;
Rinaldi, S ;
Sambri, L .
TETRAHEDRON LETTERS, 2002, 43 (36) :6331-6333
[2]  
BASTOCK TW, 1994, J CHEM RES-S, P104
[3]  
*CHEM RUBB CO, 1967, CRC HDB TABL ORG COM
[4]   FRIEDEL-CRAFTS ACYLATION OF TOLUENE AND PARA-XYLENE WITH CARBOXYLIC-ACIDS CATALYZED BY ZEOLITES [J].
CHICHE, B ;
FINIELS, A ;
GAUTHIER, C ;
GENESTE, P ;
GRAILLE, J ;
PIOCH, D .
JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (11) :2128-2130
[5]  
CORNELIS A, 1986, CHEM REACTIONS ORGAN, P212
[6]   Acylation of resorcinol on clay catalysts [J].
Farkas, J ;
Békássy, S ;
Agai, B ;
Hegedus, M ;
Figueras, F .
SYNTHETIC COMMUNICATIONS, 2000, 30 (14) :2479-2485
[7]   Preparation of α-ketophosphonates by oxidation of α-hydroxyphosphonates with neutral alumina supported potassium permanganate (NASPP) under solvent-free conditions and potassium permanganate in dry benzene [J].
Firouzabadi, H ;
Iranpoor, N ;
Sobhani, S .
TETRAHEDRON LETTERS, 2002, 43 (03) :477-480
[8]   High yield preparation of a-ketophosphonates by oxidation of α-hydroxyphosphonates with zinc dichromate trihydrate (ZnCr2O7•3H2O) under solvent-free conditions [J].
Firouzabadi, H ;
Iranpoor, N ;
Sobhani, S ;
Sardarian, AR .
TETRAHEDRON LETTERS, 2001, 42 (26) :4369-4371
[9]   The catalytic friedel-crafts acylation reaction of aromatic compounds with carboxylic anhydrides using combined catalyst system of titanium(IV) chloride tris(trifluoromethanesulfonate) and trifluoromethanesulfonic acid [J].
Izumi, J ;
Mukaiyama, T .
CHEMISTRY LETTERS, 1996, (09) :739-740
[10]  
KAWADA A, 1996, J CHEM SOC CHEM COMM, P183